Boryl-substituted low-valent heavy group 14 compounds

Literature Information

Publication Date 2023-12-12
DOI 10.1039/D3CS00791J
Impact Factor 54.564
Authors

Chenxi Duan, Chunming Cui


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Abstract

Low valent group 14 compounds exhibit diverse structures and reactivities. The employment of diazaborolyl anions (NHB anions), isoelectronic analogues to N-heterocyclic carbenes (NHCs), in group 14 chemistry leads to the exceptional structures and reactivity. The unique combination of σ-electron donation and pronounced steric hindrance impart distinct structural characteristics to the NHB-substituted low valent group 14 compounds. Notably, the modulation of the HOMO–LUMO gap in these compounds with the diazaborolyl substituents results in novel reaction patterns in the activation of small molecules and inert chemical bonds. This review mainly summarizes the recent advances in NHB-substituted low-valent heavy Group 14 compounds, emphasizing their synthesis, structural characteristics and application to small molecule activation.

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Chemical Society Reviews

Chemical Society Reviews
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Chem Soc Rev publishes review articles covering important topics at the forefront of the chemical sciences. Reviews should be of the very highest quality and international impact. We particularly encourage international and multidisciplinary collaborations among our authors. Our scope covers the breadth of the chemical sciences, including interdisciplinary topics where the article has a basis in chemistry. Topics include: Analytical chemistry Biomaterials chemistry Bioorganic/medicinal chemistry Catalysis Chemical Biology Coordination Chemistry Crystal Engineering Energy Sustainable chemistry Green chemistry Inorganic chemistry Inorganic materials Main group chemistry Nanoscience Organic chemistry Organic materials Organometallics Physical chemistry Supramolecular chemistry Synthetic methodology Theoretical and computational chemistry

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