Photoredox sheds new light on nickel catalysis: from carbon–carbon to carbon–heteroatom bond formation
Literature Information
Publication Date
2016-02-03
DOI
10.1039/C5QO00437C
Impact Factor
5.281
Authors
Yong-Yuan Gui, Liang Sun, Zhi-Peng Lu, Da-Gang Yu
View Original
Abstract
This highlight describes the recent emergence of photoredox/nickel dual catalysis to generate carbon–carbon and carbon–heteroatom bonds. To address the challenges in traditional nickel-catalyzed couplings, the application of photoredox catalysis facilitates transmetallation via single-electron transfer and generation of highly reactive nickel(III) intermediates to promote reductive elimination, thus providing new opportunities for nickel-catalysis.
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Source Journal
Organic Chemistry Frontiers
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