Pyrazolate vs. phenylethynide: direct exchange of the anionic bridging ligand in a cyclic trinuclear silver complex

Literature Information

Publication Date 2023-12-11
DOI 10.1039/D3CC05659G
Impact Factor 6.222
Authors

Aleksei A. Titov, Andrey Yu. Chernyadyev, Ivan A. Godovikov, Oleg A. Filippov, Elena S. Shubina


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Abstract

Cyclic trinuclear Ag(I) pyrazolate interacts with phenylacetylene forming a mix-ligand complex in which one pyrazolate ligand is changed to phenylethynide. The CC− fragment coordinates only to two silver(I) atoms via one carbon atom demonstrating unique μ2-η1 σ-coordination with close Ag–C bond lengths and Ag–C–C angles. The complex exhibits blue emission under UV irradiation.

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