Pyrazolate vs. phenylethynide: direct exchange of the anionic bridging ligand in a cyclic trinuclear silver complex
Literature Information
Aleksei A. Titov, Andrey Yu. Chernyadyev, Ivan A. Godovikov, Oleg A. Filippov, Elena S. Shubina
Cyclic trinuclear Ag(I) pyrazolate interacts with phenylacetylene forming a mix-ligand complex in which one pyrazolate ligand is changed to phenylethynide. The CC− fragment coordinates only to two silver(I) atoms via one carbon atom demonstrating unique μ2-η1 σ-coordination with close Ag–C bond lengths and Ag–C–C angles. The complex exhibits blue emission under UV irradiation.
Related Literature
Resistive switching properties of epitaxial BaTiO3−δ thin films tuned by after-growth oxygen cooling pressure
Yooun Heo, Daisuke Kan, Jan Seidel
DOI: 10.1039/C5CP05333A
New insights into UTSA-16
Alessio Masala, Jenny G. Vitillo, Francesca Bonino, Maela Manzoli, Carlos A. Grande, Silvia Bordiga
DOI: 10.1039/C5CP05905D
Doping liquid crystals with nanoparticles. A computer simulation of the effects of nanoparticle shape
Silvia Orlandi, Erika Benini, Isabella Miglioli, Dean R. Evans, Victor Reshetnyak, Claudio Zannoni
DOI: 10.1039/C5CP05754J
Supported lipid bilayer repair mediated by AH peptide
Anders Gunnarsson, Fredrik Höök
DOI: 10.1039/C5CP06472D
Rotational spectroscopy of the atmospheric photo-oxidation product o-toluic acid and its monohydrate
Elijah G. Schnitzler, Brandi L. M. Zenchyzen, Wolfgang Jäger
DOI: 10.1039/C5CP06073G
Ultrasonically treated liquid interfaces for progress in cleaning and separation processes
Darya Radziuk, Helmuth Möhwald
DOI: 10.1039/C5CP05142H
Origins of ultralow thermal conductivity in bulk [6,6]-phenyl-C61-butyric acid methyl ester (PCBM)
Jan-Hendrik Pöhls
DOI: 10.1039/C5CP06575E
Intensified effects of multi-Cu modification on the electronic properties of the modified base pairs containing hetero-ring-expanded pyrimidine bases
Yuxiang Bu, Huatian Wang
DOI: 10.1039/C5CP06133D
Unexpected multiple activated steps in the excited state decay of some bis(phenylethynyl)-fluorenes and -anthracenes
G. Cacioppa, B. Carlotti, F. Elisei, P. L. Gentili, A. Marrocchi, A. Spalletti
DOI: 10.1039/C5CP06025G
Deep traps can reduce memory effects of shallower ones in scintillators
Federico Moretti, Gaël Patton, Andrei Belsky, Ashot G. Petrosyan, Christophe Dujardin
DOI: 10.1039/C5CP05711F
You might also like
How should waste containing 6-Chloro-5-(2'-hydroxy-3'-methoxy-4-biphenylyl)-3-(3-methoxyphenyl)-1H-pyrrolo[3,2-d]pyrimidine-2,4(3H,5H)-dione (CAS: 1346607-05-3) be handled?
Waste containing 6-Chloro-5-(2'-hydroxy-3'-methoxy-4-biphenylyl)-3-(3-methoxyphe...
What are the main uses of (3alpha,5alpha)-3-Hydroxypregnane-11,20-dione (CAS: 23930-19-0)?
(3alpha,5alpha)-3-Hydroxypregnane-11,20-dione is primarily used in the pharmaceu...
What is the market or research trend for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4)?
The market for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4) is ...
Are there alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in synthesis?
Alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in ...
Is N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) safe?
N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) is generally safe...
Are there alternatives to [(4R,5R,6S)-5-hydroxy-10-imino-3,7-dioxa-1,9-diazatricyclo[6.4.0.02,6]dodeca-8,11-dien-4-yl]methyl dihydrogen phosphate (CAS: 39679-56-6) in synthesis?
Alternative reagents such as other phosphates or similar functional groups can b...
Are there alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-14-5) in synthesis?
There are alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-...
What precautions should be taken when handling Aluminium trihexadecanoate (CAS: 555-35-1)?
When handling Aluminium trihexadecanoate, it is important to use appropriate per...
What is (1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid (CAS: 52188-11-1)?
(1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid is a chemical compound ...
Are there alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) in synthesis?
Several alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) can be used in...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











![5'-Fluoro-[2,3'-biindolinylidene]-2',3-dione structure 5'-Fluoro-[2,3'-biindolinylidene]-2',3-dione structure](https://static.chemtradehub.com/structs/251/251903-00-1-9cb1.webp)


