5- and 10-oxocorroles from β-octaalkylcorroles

Literature Information

Publication Date 2023-11-20
DOI 10.1039/D3CC05204D
Impact Factor 6.222
Authors

Lorena Di Zazzo, Sara Nardis, Fabrizio Caroleo, Francesco Pizzoli, Frank R. Fronczek, Kevin M. Smith, Beatrice Berionni Berna, Roberto Paolesse


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Abstract

The reaction of Zn ions with β-octaalkylcorroles leads to the air oxidation of the macrocycle, with the formation of a mixture of 5- and 10-oxocorroles. Spectroscopic characterization confirms the antiaromatic character of these macrocycles. A simple synthetic protocol opens the way for more detailed studies of oxocorrole chemistry.

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DOI: 10.1039/D2RE90002E

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