Intramolecular through-space charge transfer between benzofuran and ynone groups on a naphthalene spacer
Literature Information
Eylul Calikyilmaz, Gozde Karaoglu, Mete Demir, Onur Şahin, Burak Ulgut, Akin Akdag
We have developed a new scaffold that exhibits an efficient intramolecular through-space charge transfer (CT). In this design, electron-rich benzofuran and electron-deficient ynone groups are placed strategically in proximity via a naphthalene spacer. Charge transfer is supported by distinct CT bands in the visible region (>500 nm) in their UV-vis absorption and emission spectra.
Recommended Journals

Journal of Physics and Chemistry of Solids

European Journal of Wood and Wood Products

Pure and Applied Chemistry

Journal of Heterocyclic Chemistry

Organic Preparations and Procedures International

Science

Nature

Proceedings of the National Academy of Sciences of the United States of America

Journal of Catalysis

Israel Journal of Chemistry
Related Literature
Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT molecules
Xun Zhang, Siping Hu, Qiang Ma
DOI: 10.1039/D0PY00369G
Rapid production of block copolymer nano-objects via continuous-flow ultrafast RAFT dispersion polymerisation
Sam Parkinson, Stephen T. Knox, Richard A. Bourne, Nicholas J. Warren
DOI: 10.1039/D0PY00276C
A 3D printed drug delivery implant formed from a dynamic supramolecular polyurethane formulation
S. Salimi, Y. Wu, M. I. Evangelista Barreiros, A. A. Natfji, S. Khaled, R. Wildman, L. R. Hart, F. Greco, E. A. Clark, C. J. Roberts, W. Hayes
DOI: 10.1039/D0PY00068J
Highly active bimetallic nickel catalysts for alternating copolymerization of carbon dioxide with epoxides
Yu-Chia Su, Chih-Hsiang Tsui, Chen-Yen Tsai, Bao-Tsan Ko
DOI: 10.1039/D0PY00174K
A general method to greatly enhance ultrasound-responsiveness for common polymeric assemblies
Jinkang Dou, Ruiqi Yang, Kun Du, Li Jiang, Xiayun Huang, Daoyong Chen
DOI: 10.1039/D0PY00254B
Preparation of aryl polysulfonates via a highly efficient SuFEx click reaction, their controllable degradation and functionalized behavior
Zhenlei Cao, Feng Zhou, Pei-Yang Gu, Dongyun Chen, Jinghui He, John R. Cappiello, Peng Wu, Qingfeng Xu, Jianmei Lu
DOI: 10.1039/D0PY00435A
Metal-free polycycloaddition of aldehyde-activated internal diynes and diazides toward post-functionalizable poly(formyl-1,2,3-triazole)s
Baixue Li, Anjun Qin
DOI: 10.1039/D0PY00193G
You might also like
How should waste containing 6-Chloro-5-(2'-hydroxy-3'-methoxy-4-biphenylyl)-3-(3-methoxyphenyl)-1H-pyrrolo[3,2-d]pyrimidine-2,4(3H,5H)-dione (CAS: 1346607-05-3) be handled?
Waste containing 6-Chloro-5-(2'-hydroxy-3'-methoxy-4-biphenylyl)-3-(3-methoxyphe...
What are the main uses of (3alpha,5alpha)-3-Hydroxypregnane-11,20-dione (CAS: 23930-19-0)?
(3alpha,5alpha)-3-Hydroxypregnane-11,20-dione is primarily used in the pharmaceu...
What is the market or research trend for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4)?
The market for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4) is ...
Are there alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in synthesis?
Alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in ...
Is N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) safe?
N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) is generally safe...
Are there alternatives to [(4R,5R,6S)-5-hydroxy-10-imino-3,7-dioxa-1,9-diazatricyclo[6.4.0.02,6]dodeca-8,11-dien-4-yl]methyl dihydrogen phosphate (CAS: 39679-56-6) in synthesis?
Alternative reagents such as other phosphates or similar functional groups can b...
Are there alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-14-5) in synthesis?
There are alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-...
What precautions should be taken when handling Aluminium trihexadecanoate (CAS: 555-35-1)?
When handling Aluminium trihexadecanoate, it is important to use appropriate per...
What is (1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid (CAS: 52188-11-1)?
(1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid is a chemical compound ...
Are there alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) in synthesis?
Several alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) can be used in...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

![2-Methyl-2-propanyl (2E)-5-chloro-2-[3-methoxy-4-(4-methyl-1H-imidazol-1-yl)benzylidene]pentanoate structure 2-Methyl-2-propanyl (2E)-5-chloro-2-[3-methoxy-4-(4-methyl-1H-imidazol-1-yl)benzylidene]pentanoate structure](https://static.chemtradehub.com/structs/122/1225232-42-7-ee03.webp)


