A Co(TAML)-based artificial metalloenzyme for asymmetric radical-type oxygen atom transfer catalysis

Literature Information

Publication Date 2023-11-14
DOI 10.1039/D3CC04723G
Impact Factor 6.222
Authors

Eva J. Meeus, Nico V. Igareta, Iori Morita, Thomas R. Ward, Bas de Bruin, Joost N. H. Reek


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Abstract

We show that the incorporation of a biotinylated Co(TAML) cofactor within streptavidin enables asymmetric radical-type oxygen atom transfer catalysis with improved activity and enantioselectivity.

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