A Co(TAML)-based artificial metalloenzyme for asymmetric radical-type oxygen atom transfer catalysis
Literature Information
Eva J. Meeus, Nico V. Igareta, Iori Morita, Thomas R. Ward, Bas de Bruin, Joost N. H. Reek
We show that the incorporation of a biotinylated Co(TAML) cofactor within streptavidin enables asymmetric radical-type oxygen atom transfer catalysis with improved activity and enantioselectivity.
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