An environment friendly electrochemical synthesis of 1,1,4,4-tetramethyl-2-tetrazene energetic materials from undimethylhydrazine
Literature Information
Publication Date
2023-11-07
DOI
10.1039/D3CC04693A
Impact Factor
6.222
Authors
Qi Xue, Mi Zhang, Liang He, Fu-Qing Bi, Bo-Zhou Wang, Bin Liu
View Original
Abstract
As a prospective alternative liquid propellant, 1,4,4-tetramethyl-2-tetrazene (TMTZ) possesses high enthalpy of formation and environment friendly decomposition products, and shows a promising application prospect in aerospace, munitions manufacturing, etc. An environment friendly and convenient synthesis of TMTZ through electrochemical oxidative coupling of undimethylhydrazine (UDMH) on commercially procured electrodes was carried out under mild conditions, in which the purity is up to 98.5% with a yield of over 45%. It is a simple, clean and suitable method for industrial production in contrast with the previously reported conventional chemical oxidation syntheses.
Related Literature
Assignment of absolute configuration of a chiral phenyl-substituted dihydrofuroangelicin
Gennaro Pescitelli, Nina Berova, Tom L. Xiao, Roman V. Rozhkov, Richard C. Larock, Daniel W. Armstrong
2002-12-03
Paper
DOI: 10.1039/B207652G
Fe-Catalyzed tandem cyclization for the synthesis of 3-nitrofurans from homopropargylic alcohols and Al(NO3)3·9H2O
Ting Wang, Yong Jiang, Yanyan Wang, Rulong Yan
2018-07-02
Communication
DOI: 10.1039/C8OB01184B
1,2-Chlorine atom migration in 3-chloro-2-butyl radicals: a computational study
Bernd Neumann, Hendrik Zipse
2002-11-26
Paper
DOI: 10.1039/B209981K
An effective preparation of both 1,3-diketones and nitriles from alkynones with oximes as hydroxide sources
Pei Chen, Qian-Qian Zhang, Jia Guo, Lu-Lu Chen, Yan-Bo Wang, Xiao Zhang
2018-09-03
Paper
DOI: 10.1039/C8OB01861H
Preferential precipitation of C70 over C60 with p-halohomooxacalix[3]arenes
Naoki Komatsu
2002-11-27
Paper
DOI: 10.1039/B208107E
Formal reductive addition of acetonitrile to aldehydes and ketones‡
Karim Muratov, Ekaterina Kuchuk, Sreekumar Vellalath, Oleg I. Afanasyev, Alexei P. Moskovets, Gleb Denisov, Denis Chusov
2018-09-28
Paper
DOI: 10.1039/C8OB01992D
Tuning the biomimetic performances of 4-hydroxyproline-containing cyclic peptoids
R. Schettini, C. Costabile, G. Della Sala, J. Buirey, M. Tosolini, P. Tecilla, M. C. Vaccaro, I. Bruno, F. De Riccardis, I. Izzo
2018-08-27
Paper
DOI: 10.1039/C8OB01522H
Catalytic asymmetric Henry reactions of silyl nitronates with aldehydes
Tine Risgaard, Kurt V. Gothelf, Karl Anker Jørgensen
2002-12-03
Paper
DOI: 10.1039/B208859M
Azodicarboxylate-free esterification with triphenylphosphine mediated by flavin and visible light: method development and stereoselectivity control
Michal März, Michal Kohout, Tomáš Neveselý, Josef Chudoba, Dorota Prukała, Stanislaw Niziński, Marek Sikorski, Gotard Burdziński, Radek Cibulka
2018-09-03
Paper
DOI: 10.1039/C8OB01822G
Möbius bis and tris-spiroaromatic systems
David Hall, Henry S. Rzepa
2002-12-02
Paper
DOI: 10.1039/B210415F
You might also like
Compound Q&A
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
628-39-7Diethyldiselane
Compound Q&A
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
4857-42-53-Methyl-1,2-oxazole...
Compound Q&A
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
1281816-04-3Lys-SMCC-DM1
Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![5'-Fluoro-[2,3'-biindolinylidene]-2',3-dione structure](https://static.chemtradehub.com/structs/251/251903-00-1-9cb1.webp "5'-Fluoro-[2,3'-biindolinylidene]-2',3-dione structure")
![1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone structure](https://static.chemtradehub.com/structs/122/1226872-27-0-e037.webp "1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone structure")
1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone
CAS Number:
1226872-27-0
Molecular Formula:
C25H26N6O4
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.