Creating glassy states of dicarboxylate-bridged coordination polymers
Literature Information
Zeyu Fan, Yong-Sheng Wei, Chinmoy Das, Kazuyoshi Kanamori, Hiroki Yamada, Koji Ohara
We report the direct formation of dicarboxylate-based coordination polymer glasses through thermal dehydration. The rearrangement of the coordination networks caused by dehydration was monitored by in situ powder X-ray diffraction, infrared spectroscopy, and synchrotron X-ray characterizations. The microporosity and mechanical properties of these glasses were investigated.
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