A heteropolytungstate based 2D layered porous framework with high proton conductivity
Literature Information
Publication Date
2023-10-17
DOI
10.1039/D3CC04517J
Impact Factor
6.222
Authors
Mengnan Yang, Yao Zhang, Shiyan Ji, Huafeng Li, Xinyi Ma, Yuzhen Jin, Pengtao Ma, Jingping Wang, Jingyang Niu
View Original
Abstract
A heteropolytungstate cluster [{Ru2O(bpy)2}2{Bi2W32O110}]10− (bpy = C10H8N2) was incorporated into a 2 : 1 type layered porous framework by interweaving the Na+ bridged cluster chains through the hydrogen bonding ability of the bpy ligands. It features multiple pore channels rich in hydrogen-bond network, contributing high conductivities > 10−2 S cm−1 at 298–358 K and 85% RH.
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