Carborane-based heteromolecular extended networks driven by directional C–Te⋯N chalcogen bonding interactions
Literature Information
Maxime Beau, Olivier Jeannin, Marc Fourmigué, Emmanuel Aubert, Enrique Espinosa, Sunhee Lee, Won-Sik Han, Ie-Rang Jeon
We demonstrate that o-closo-(TeMe)2carborane directs, in the presence of linear ditopic neutral Lewis bases, the formation of co-crystals with 1D extended supramolecular networks. Specifically, the network formation is systematically stabilized by short and quasi-linear C–Te⋯N chalcogen-bonding (ChB) interactions. In sum, we report efficient carborane-based tectons to rationally design high-dimensional neutral heteromolecular networks.
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