Direct C–S bond formation via C–O bond activation of phenols in a crossover Pd/Cu dual-metal catalysis system

Literature Information

Publication Date 2019-04-10
DOI 10.1039/C9OB00313D
Impact Factor 3.876
Authors

Vahid Khakyzadeh, Abed Rostami, Hojat Veisi, Behzad Shirmardi Shaghasemi, Erik Reimhult, Yuanzhi Xia, Sima Darvishi


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Abstract

A dual-metal catalysis system including a newly prepared nanoparticle [SiO2@organic-linker(OL)@Pd(II)] and CuI was introduced with ultra-high catalytic activity (high turnover number (TON), up to 19 000) to a one-pot and odorless synthesis of unsymmetrical aryl sulfides by crossover C–S bond formation. The reaction proceeds via C–O bond activation of phenols and direct C–S bond formation in the presence of S8 as an oddorless sulfur source and aryl boronic acids under mild conditions (room temperature). The catalyst could be recycled up to five times without an obvious change in its activity.

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Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
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