Chemical pressure-induced PtIII–I Mott–Hubbard nanowire, [Pt(en)2I](Asp-Cn)2·H2O (13 ≤ n), detected via polarized infrared spectroscopy

Literature Information

Publication Date 2023-11-01
DOI 10.1039/D3CC04285E
Impact Factor 6.222
Authors

Shohei Kumagai, Takefumi Yoshida, Hiroaki Iguchi, Masanori Wakizaka, Nobuto Funakoshi, Shinya Takaishi


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Abstract

The electronic states of iodo-bridged platinum nanowire complexes have been studied using polarized FT-IR spectroscopy. The N–H symmetrical stretching mode was found to be highly sensitive to the electronic states, distinguishing mixed-valence (MV) and averaged-valence (AV) states. The first Pt(III) nanowire complexes have been realized by the chemical pressures of the counter-anions.

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Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
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