The role of char-forming processes in the thermal decomposition of cellulose
Literature Information
A simple model for the thermal decomposition of amorphous cellulose is proposed that rationalizes the effect of water in promoting the charring process at the expense of volatilization. Simulations of mass-loss histories and product evolution are shown to be consistent with various experimental observations in the literature. Under char-promoting conditions where heat transfer is limited, anomalous thermal effects are predicted which indicate that char formation may not always be desirable in fire-inhibiting treatments of or strategies for cellulosic materials.
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Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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