Modulation of single-chain magnet behaviour in a heterometallic Fe2Co cyanide-bridged 2D sheet

Literature Information

Publication Date 2023-12-14
DOI 10.1039/D3CC03647B
Impact Factor 6.222
Authors

Ranjan Kharel, Jyoti Yadav, Sanjit Konar


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Abstract

A cyanide-bridged Fe2Co 2D sheet exhibiting electron transfer coupled spin transition (ETCST) with co-existence of magnetic ordering below 50 K is reported. The complex exhibits single-chain magnet behaviour where the uncoordinated water molecules act as an exchange-breaking impurity by allowing only a fraction of the molecule to undergo a spin state change. The paramagnetic centres prevail throughout the chain on desolvation, thereby increasing the number of correlated units in the chain.

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