Trapping of soluble, KCl-stabilized Cu(i) hydrides with CO2 gives crystalline formates

Literature Information

Publication Date 2023-11-07
DOI 10.1039/D3CC03033D
Impact Factor 6.222
Authors

Alexander Grasruck, Giorgio Parla, Lisha Lou, Jens Langer, Christian Neiß, Alberto Herrera, Sybille Frieß, Andreas Görling, Günter Schmid, Romano Dorta


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Abstract

Cu(I)-Hydrido complexes supported by dibenzo[b,f]azepinyl P-alkene hybrid ligands and stabilized by electrostatic interactions in a Cu–H⋯KCl⋯BR3 arrangement can be trapped with CO2 at low temperature to afford Cu(I)-formates. The complexes are isolable with and without a pendant BEt3 group and show strong Cu–O and weak B–O interactions.

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