Trapping of soluble, KCl-stabilized Cu(i) hydrides with CO2 gives crystalline formates
Literature Information
Alexander Grasruck, Giorgio Parla, Lisha Lou, Jens Langer, Christian Neiß, Alberto Herrera, Sybille Frieß, Andreas Görling, Günter Schmid, Romano Dorta
Cu(I)-Hydrido complexes supported by dibenzo[b,f]azepinyl P-alkene hybrid ligands and stabilized by electrostatic interactions in a Cu–H⋯KCl⋯BR3 arrangement can be trapped with CO2 at low temperature to afford Cu(I)-formates. The complexes are isolable with and without a pendant BEt3 group and show strong Cu–O and weak B–O interactions.
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![(3S,4aS,8aS)-2-[(2R,3S)-3-Amino-2-hydroxy-4-phenylbutyl]-N-(2-methyl-2-propanyl)decahydro-3-isoquinolinecarboxamide structure (3S,4aS,8aS)-2-[(2R,3S)-3-Amino-2-hydroxy-4-phenylbutyl]-N-(2-methyl-2-propanyl)decahydro-3-isoquinolinecarboxamide structure](https://static.chemtradehub.com/structs/136/136522-17-3-4d77.webp)



