Metallosupramolecular polymers as precursors for platinum nanocomposites

Nanocomposites comprising a polymer matrix and metallic nanoparticles (NPs) can merge the structural features of the matrix material with the functional characteristics of the NPs. While such materials are promising for a wide range of applications, their preparation typically requires multi-step processes that can be difficult to control. Alternatively, materials with NPs can be directly accessed in a controlled manner by exploiting zero-valent metallosupramolecular polymer (MSP) precursors. We here report how the nature of the polymer and its molecular weight affect the nanocomposite formation and structure. Poly(tetrahydrofuran)-based macromonomers with suitable ligands are used to prepare MSPs based on bis(η2-alkyne)platinum(0) complexes. Heating these materials causes disassembly of the complexes and, upon the release of Pt0-atoms, Pt-NPs form in the matrix polymer. The Pt content in the MSP influences the NP formation and thereby the characteristics of the nanocomposites. It is also possible to trigger the complex dissociation and NP formation by exposure to UV light. This allows photolithographic processing and thus the preparation of nanocomposites that contain Pt-NPs in a spatially controlled manner.