![4-[2-(Trichlorosilyl)ethyl]benzenesulfonyl chloride structure](https://static.chemtradehub.com/structs/797/79793-00-3-de16.webp "4-[2-(Trichlorosilyl)ethyl]benzenesulfonyl chloride structure")
4-[2-(Trichlorosilyl)ethyl]benzenesulfonyl chloride
CAS Number:
79793-00-3
Molecular Formula:
C8H8Cl4O2SSi
RhIII-Catalyzed formal [5 + 1] cyclization of 2-pyrrolyl/indolylanilines using vinylene carbonate as a C1 synthon
Literature Information
Publication Date
2021-02-08
DOI
10.1039/D1QO00040C
Impact Factor
5.281
Authors
Jiang Nan, Qiong Ma, Jiacheng Yin, Chengyuan Liang, Lei Tian, Yangmin Ma
View Original
Abstract
A rhodium(III)-catalyzed formal C–H [5 + 1] cyclization of 2-pyrrolyl/indolylanilines with vinylene carbonate has been explored towards the potent assembly of diverse 4-methylpyrrolo[1,2-a]quinoxalines. This established protocol is characterized by an exceedingly simple reaction system, and excellent functional group toleration and yields. Most importantly, entirely distinct from documented [4 + 2] cyclization conversions, herein, the emerging vinylene carbonate firstly presents as a C1 synthon to realize [5 + 1] annulation and shows new chemical reactivity. Biological studies indicate that these prepared products are promising candidates in terms of their antibacterial activity.
Related Literature
Effective stabilisation of α-helical structures in short peptides with acetylenic cross-linking agents
Kazuhisa Fujimoto, Natsuko Oimoto, Kahori Katsuno, Masahiko Inouye
2004-05-10
Communication
DOI: 10.1039/B403615H
An unprecedented rhodium-catalysed self-conjugate reduction, cross-coupling tandem reaction of cinnamaldehydes with arylboronic acids
Zhiyong Wang, Gang Zou, Jie Tang
2004-04-14
Communication
DOI: 10.1039/B401511H
Javaniside, a novel DNA cleavage agent from Alangium javanicum having an unusual oxindole skeleton
Ji Ma, Sidney M. Hecht
2004-04-14
Communication
DOI: 10.1039/B402925A
Crystal engineering of urea α-network via I⋯O2N synthon and design of SHG active crystal N-4-iodophenyl-N′-4′-nitrophenylurea
Sumod George, Ashwini Nangia, Chi-Keung Lam, Thomas C. W. Mak, Jean-François Nicoud
2004-04-20
Communication
DOI: 10.1039/B402050B
Poly(vinyl alcohol) star polymers prepared via MADIX/RAFT polymerisation
Martina H. Stenzel, Thomas P. Davis, Christopher Barner-Kowollik
2004-06-02
Communication
DOI: 10.1039/B404763J
Stereospecific peptide folds. A rationally designed molecular bracelet
Soumendra Rana, Bijoy Kundu, Susheel Durani
2004-09-20
Communication
DOI: 10.1039/B410532J
Ring-closing metathesis in biphasic BMI·PF6ionic liquid/toluene medium: a powerful recyclable and environmentally friendly process
Hervé Clavier, Nicolas Audic, Marc Mauduit, Jean-Claude Guillemin
2004-08-25
Communication
DOI: 10.1039/B407964G
Y-shaped two-photon absorbing molecules with an imidazole–thiazole core
Ke Feng, Leonardo De Boni, Lino Misoguti, C. R. Mendonça, Michael Meador, Fu-Lian Hsu, Xiu R. Bu
2004-04-21
Communication
DOI: 10.1039/B402019G
New, highly acidic ionic liquid systems and their application in the carbonylation of toluene
Nicole Brausch, Andreas Metlen, Peter Wasserscheid
2004-05-21
Communication
DOI: 10.1039/B403464C
Desymmetrization of meso-dienyne by asymmetric Pauson–Khand type reaction catalysts
Nakcheol Jeong, Dong Hoon Kim, Jun Hun Choi
2004-04-08
Communication
DOI: 10.1039/B401288G
You might also like
Compound Q&A
What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?
When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...
71193-32-32-Chloro-1,2-bis(4-m...
Compound Q&A
What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?
4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...
224789-26-84-Ethoxy-3-(5-methyl...
Compound Q&A
How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?
Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...
2681-55-2Methyl 3-Oxo-4-Andro...
Compound Q&A
What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?
(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...
909725-61-7(R)-3-Amino-4-(3-hex...
Compound Q&A
What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?
2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...
1254120-14-32-Methyl-2-propanyl ...
Compound Q&A
Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?
There are alternative reagents that can be used in synthesis instead of (E)-4-(t...
135355-96-3(E)-4-(tert-Butoxy)-...
Compound Q&A
What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?
[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...
121202-20-8[2-(3-Chlorophenyl)-...
Compound Q&A
What is the market or research trend for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]{[(4-methylphenyl)sulfonyl]oxy}acetate (CAS: 166249-17-8)?
The market and research trends for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4...
166249-17-8Methyl (2S)-[(4S)-2,...
Compound Q&A
What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?
The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...
42865-19-01-Bromo-2-isocyanato...
Compound Q&A
What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?
4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...
147065-06-34-Nitro-D-phenylalan...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
2-Chloro-4-nitrophenyl 6-deoxy-alpha-L-galactopyranoside
CAS Number:
157843-41-9
Molecular Formula:
C12H14ClNO7
N-(2,6-Dimethylphenyl)-2-methoxy-N-(2-oxo-1,3-oxazolidin-3-yl)acetamide
CAS Number:
77732-09-3
Molecular Formula:
C14H18N2O4
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.