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Ring-closing metathesis in biphasic BMI·PF6ionic liquid/toluene medium: a powerful recyclable and environmentally friendly process
Literature Information
Publication Date
2004-08-25
DOI
10.1039/B407964G
Impact Factor
6.222
Authors
Hervé Clavier, Nicolas Audic, Marc Mauduit, Jean-Claude Guillemin
View Original
Abstract
Biphasic BMI·PF6/toluene solvent is a remarkably suitable and clean medium for performing olefin metathesis with a new 2nd generation ionic liquid supported-ruthenium catalyst: high levels of recyclability and reusability combined with a high reactivity were obtained with a variety of di- or tri-substituted and/or oxygen-containing dienes, and very low residual ruthenium levels were detected (1 to 22 ppm) in the products.
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Source Journal
Chemical Communications
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