Synthesis and sequencing of informational poly(amino phosphodiester)s
Literature Information
Publication Date
2021-09-13
DOI
10.1039/D1PY01052B
Impact Factor
5.582
Authors
Ian Roszak, Laurence Oswald, Abdelaziz Al Ouahabi, Eline Laurent, Olivier Felix, Isaure Carvin-Sergent, Laurence Charles, Jean-François Lutz
View Original
Abstract
Sequence-defined poly(amino phosphodiester)s containing main-chain tertiary amines were synthesized by automated solid-phase phosphoramidite chemistry. These polymers were prepared using four monomers with different substituents. The formed polymers were characterized by HPLC and mass spectrometry. These methods evidenced preparation of molecularly-defined polymers. Furthermore, the presence of tertiary amines in the polymer backbones facilitates sequencing by tandem mass spectrometry.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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N-Methyl-3-(1-naphthyloxy)-3-(2-thienyl)-1-propanamine hydrochloride (1:1)
CAS Number:
1188266-11-6
Molecular Formula:
C18H20ClNOS
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