Bis(terpyridine) Ru(iii) complex functionalized porous polycarbazole for visible-light driven chemical reactions
Literature Information
Publication Date
2021-07-02
DOI
10.1039/D1PY00527H
Impact Factor
5.582
Authors
Hai-Peng Liang
View Original
Abstract
The transformation of organic molecules into compounds of interest by the utilization of solar energy is an innovative approach that is attracting a lot of attention from material scientists. Introducing potent chelation sites onto a porous matrix is imperative for the purpose of effectively recycling cost-prohibitive catalysts, e.g., ruthenium and iridium complexes. To this end, bis(terpyridine) Ru(III) complex functionalized porous polycarbazoles, CPOP-32-Ru and CPOP-32-Ru′, were synthesized. Both polymers showed high thermal stability and efficient photocatalytic activities toward a range of important organic transformations, including amine coupling, aerobic hydroxylation of arylboronic acids, and selective oxidation of sulfides.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Recommended Compounds
![(3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid structure](https://static.chemtradehub.com/structs/218/218608-96-9-f871.webp "(3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid structure")
(3R)-4-(4-Chlorophenyl)-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)butanoic acid
CAS Number:
218608-96-9
Molecular Formula:
C15H20ClNO4
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