(κ2-P,S)Pt(benzyl) complexes derived from 1/3-PiPr2-2-StBu-indene: facile synthesis of carbanion- and borate-containing zwitterions

Literature Information

Publication Date 2008-10-06
DOI 10.1039/B813421A
Impact Factor 6.222
Authors

Kevin D. Hesp, Robert McDonald, Michael J. Ferguson, Gabriele Schatte, Mark Stradiotto


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Abstract

The versatile new ligand precursor 1/3-PiPr2-2-StBu-indene has been employed in the preparation of neutral and cationic (κ2-P,S)Pt(benzyl) complexes, as well as structurally related zwitterions in which the formally cationic metal fragment is counterbalanced by an uncoordinated indenide or borate fragment that is contained within the ancillary ligand backbone.

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