Achieving molecular weight distribution shape control and broad dispersities using RAFT polymerizations
Literature Information
Publication Date
2021-04-12
DOI
10.1039/D1PY00399B
Impact Factor
5.582
Authors
Stephanie I. Rosenbloom, Renee J. Sifri, Brett P. Fors
View Original
Abstract
Reversible addition–fragmentation chain-transfer (RAFT) polymerizations are one of the most versatile and powerful polymerization techniques for the synthesis of complex macromolecular architectures. While RAFT polymerizations often give polymers with narrow molecular weight distributions (MWDs), commodity plastics often have broad MWDs to give targeted properties and processability. Thus, new methods to precisely control both MWD breadth and shape are essential for fine-tuning polymer properties for next generation materials. Herein, we report a simple method for controlling polymer MWD features in thermally activated radical RAFT and redox activated cationic RAFT polymerizations by means of metered additions of chain transfer agents.
Recommended Journals
Related Literature
On the different roles of anions and cations in the solvation of enzymes in ionic liquids
Marco Klähn, Geraldine S. Lim, Abirami Seduraman, Ping Wu
2010-12-06
Paper
DOI: 10.1039/C0CP01509A
A method to tune the ionic current rectification of track-etched nanopores by using surfactant
Lin Wang, Yu Yan, Yanbo Xie, Long Chen
2010-11-01
Paper
DOI: 10.1039/C0CP00587H
Characterization and mechanism study of micrometer-sized secondary assembly of β-cyclodextrin
Yifeng He, Xinghai Shen, Qingde Chen, Hongcheng Gao
2010-10-29
Paper
DOI: 10.1039/C0CP00899K
The benzene+OH potential energy surface: intermediates and transition states
David S. Hollman, Andrew C. Simmonett, Henry F. Schaefer
2010-11-23
Paper
DOI: 10.1039/C0CP01607A
Structure and stability of one-dimensional o-phthalaldehyde lines on the Si(100)-2 × 1:H surface
Jin-Ho Choi, Jun-Hyung Cho
2010-11-16
Communication
DOI: 10.1039/C0CP01284J
A natural missing link between activated and downhill protein folding scenarios
Feng Liu, Caroline Maynard, Gregory Scott, Artem Melnykov, Kathleen B. Hall
2010-02-11
Paper
DOI: 10.1039/B925033F
Ion–molecule reactions of ammonia clusters with C60 aggregates embedded in helium droplets
Harald Schöbel, Christian Leidlmair, Peter Bartl, Abid Aleem, Michaela Hager, Olof Echt, Tilmann D. Märk, Paul Scheier
2010-11-12
Paper
DOI: 10.1039/C0CP01268H
Hydrogenstorage reaction over a ternary imide Li2Mg2N3H3
Yongfeng Liu, Chu Liang, Zhijun Wei, Ying Jiang, Mingxia Gao, Hongge Pan, Qidong Wang
2010-02-24
Communication
DOI: 10.1039/C000271B
Theoretical studies on the coupling interactions in H2SO4⋯HOO˙⋯(H2O)n (n = 0–2) clusters: toward understanding the role of water molecules in the uptake of HOO˙ radical by sulfuric acid aerosols
Zhiying Ma, Weihua Wang, Yazhou Zhai, Haitao Sun, Siwei Bi
2010-11-05
Paper
DOI: 10.1039/C0CP00908C
You might also like
Compound Q&A
How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?
Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...
100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A
How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?
7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...
1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A
What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?
2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...
124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A
Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?
1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...
1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A
What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?
The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...
113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A
What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?
3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...
163271-80-53-(Triisopropylsilyl...
Compound Q&A
What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?
6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...
81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A
How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?
Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...
885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A
What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?
N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...
55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A
What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?
6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...
1036756-15-66-Bromo-8-fluoro-2-q...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![5-Bromoimidazo[1,2-a]pyridine structure](https://static.chemtradehub.com/structs/692/69214-09-1-d8e2.webp "5-Bromoimidazo[1,2-a]pyridine structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.