Hydrogenstorage reaction over a ternary imide Li2Mg2N3H3

Literature Information

Publication Date 2010-02-24
DOI 10.1039/C000271B
Impact Factor 3.676
Authors

Yongfeng Liu, Chu Liang, Zhijun Wei, Ying Jiang, Mingxia Gao, Hongge Pan, Qidong Wang


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Abstract

The reaction details of hydrogen storage process of a ternary imide Li2Mg2N3H3 are elucidated for the first time. It is found that 1 mole of Li2Mg2N3H3 converts to a mixture of Mg(NH2)2–2LiH–MgNH on taking up 2 moles of H2, and that the presence of MgNH in the Mg(NH2)2–2LiH system not only alters the dehydrogenation thermodynamics but also improves the dehydrogenation kinetics.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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