Intercalation/deintercalation of solvated Mg2+ into/from graphite interlayers

Literature Information

Publication Date 2021-07-27
DOI 10.1039/D1CP02895B
Impact Factor 3.676
Authors

Masahiro Shimizu, Atsuhito Nakahigashi, Susumu Arai


View Original

Abstract

In the development of rechargeable Mg-ion batteries which are not limited by resource constraints, studies on negative electrode materials have been concentrated on efficient Mg-deposition/stripping rather than on insertion/extraction-type active materials, driven by the extremely high theoretical capacity of Mg metal (2205 mA h g−1). This work re-examined the potential of graphite, which is overlooked in electrochemical tests using a two-electrode type cell due to a large overpotential during sluggish Mg-deposition/stripping at the counter electrode caused by the passivation layer. The formation of a graphite intercalation compound (GIC) with a stage structure was demonstrated by the continual application of a constant current without considering the cut-off voltage to eliminate the detrimental impact of the counter electrode, although the intercalant was solvated Mg-ions. The GIC formed during the charging process has a blue tint just like a GIC synthesized by a vapor method. Although there is still issue with the large polarization during the deintercalation of solvated Mg ions, a reversible capacity of approximately 200 mA h g−1 could be achieved in the galvanostatic charge/discharge tests with a current density of 7.44 mA g−1. The results should facilitate future research and development of graphite as a negative electrode material.

Related Literature

Structure and binding of the H4 histone tail and the effects of lysine 16 acetylation

Darren Yang, Gaurav Arya

2010-12-15 Paper

DOI: 10.1039/C0CP01487G

Long distance energy transfer in a polymer matrix doped with a perylenedye

Franziska Fennel, Stefan Lochbrunner

2011-01-06 Paper

DOI: 10.1039/C0CP01211D

Catalytic activity of a ζ-class zinc and cadmium containing carbonic anhydrase. Compared work mechanisms

Orazio Amata, Tiziana Marino, Nino Russo, Marirosa Toscano

2011-01-07 Paper

DOI: 10.1039/C0CP01053G

In situFTIR spectroelectrochemical study on the mechanism of ethylene glycol electrocatalytic oxidation at a Pd electrode

Lianqin Wang, Hui Meng, Pei Kang Shen, Claudio Bianchini, Francesco Vizza, Zidong Wei

2010-12-08 Paper

DOI: 10.1039/C0CP01913E

The impact of protonation and deprotonation of 3-methyl-2′-deoxyadenosine on N-glycosidic bond cleavage

Ali Ebrahimi, Mostafa Habibi-Khorassani, Sophia Bazzi

2011-01-26 Paper

DOI: 10.1039/C0CP01279C

MRCI investigation of different isomers of Ni2O2H2+‡

Olaf Hübner, Hans-Jörg Himmel

2010-12-08 Paper

DOI: 10.1039/C0CP01170C

Photodegradation of organic pollutants catalyzed by iron species under visible light irradiation

Chunyan Sun, Chuncheng Chen, Wanhong Ma, Jincai Zhao

2010-11-17 Perspective

DOI: 10.1039/C0CP01203C

2D silver nanocrystal ordering modulated by various substrates and revealed using oxygen plasma treatment

Emilie Klecha, Imad Arfaoui, Johannes Richardi, Dorothée Ingert, Marie-Paule Pileni

2010-12-17 Paper

DOI: 10.1039/C0CP01237H

The role of hydrogen bonding in water–metal interactions

Adrien Poissier, Sriram Ganeshan, M. V. Fernández-Serra

2010-12-22 Paper

DOI: 10.1039/C0CP00994F

Fullerene derivative acceptors for high performance polymer solar cells

Youjun He, Yongfang Li

2010-12-22 Perspective

DOI: 10.1039/C0CP01178A

You might also like

Compound Q&A

How is Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) typically synthesized?

Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) can be synth...

59713-58-5Ethyl 4-chlorothieno...
Compound Q&A

What regulatory guidelines apply to 5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2)?

5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2) is subject to various regula...

52562-50-25-Methyl-1H-indole-3...
Compound Q&A

What are the physical and chemical properties of (1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid (CAS: 223418-73-3)?

(1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid is a white...

223418-73-3(1,3-Dimethyl-2,4-di...
Compound Q&A

How should waste containing Sulfocostunolide A (CAS: 1016983-51-9) be handled?

Waste containing Sulfocostunolide A (CAS: 1016983-51-9) should be handled with c...

1016983-51-9Sulfocostunolide A
Compound Q&A

What precautions should be taken when handling Murraxocin (CAS: 88478-44-8)?

When handling Murraxocin (CAS: 88478-44-8), ensure proper personal protective eq...

88478-44-8Murraxocin
Compound Q&A

What are the physical and chemical properties of Formvar (CAS: 63148-64-1)?

Formvar (CAS: 63148-64-1) is an alkyd resin characterized by a high molecular we...

63148-64-1Formvar(R)
Compound Q&A

Is (S)-4-benzyl-2-((benzyloxy)methyl)morpholine (CAS: 205242-66-6) safe?

(S)-4-benzyl-2-((benzyloxy)methyl)morpholine is generally safe when handled with...

205242-66-6(S)-4-benzyl-2-((ben...
Compound Q&A

What industries use Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3)?

Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3) is p...

1447607-69-3Methyl 1-(5-bromo-2-...
Compound Q&A

Is 2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) safe?

2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) is generally con...

24290-47-92-Methyl-1-phenyl-1-...
Compound Q&A

How is 3-(4-Bromophenyl)-2-methylpropanoic acid (CAS: 66735-01-1) typically synthesized?

3-(4-Bromophenyl)-2-methylpropanoic acid is synthesized through a multi-step pro...

66735-01-13-(4-Bromophenyl)-2-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.