Compositional flexibility in Li–N–H materials: implications for ammonia catalysis and hydrogen storage

Literature Information

Publication Date 2021-07-05
DOI 10.1039/D1CP02440J
Impact Factor 3.676
Authors

Joshua W. Makepeace, Alisha Sukhwani Manghnani, Claire A. Murray, Thomas J. Wood


View Original

Abstract

Li–N–H materials, particularly lithium amide and lithium imide, have been explored for use in a variety of energy storage applications in recent years. Compositional variation within the parent lithium imide, anti-fluorite crystal structure has been related to both its facile storage of hydrogen and impressive catalytic performance for the decomposition of ammonia. Here, we explore the controlled solid-state synthesis of Li–N–H solid-solution anti-fluorite structures ranging from amide-dominated (Li4/3(NH2)2/3(NH)1/3 or Li1.333NH1.667) through lithium imide to majority incorporation of lithium nitride–hydride (Li3.167(NH)0.416N0.584H0.584 or Li3.167NH). Formation of these solid solutions is demonstrated to cause significant changes to the thermal stability and ammonia reactivity of the samples, highlighting the potential use of compositional variation to control the properties of the material in gas storage and catalytic applications.

Related Literature

Unraveling non-covalent interactions within flexible biomolecules: from electron density topology to gas phase spectroscopy

R. Chaudret, B. de Courcy, J. Contreras-García, A. Zehnacker-Rentien, J.-P. Piquemal

2013-10-11 Paper

DOI: 10.1039/C3CP52774C

Excited states of protonated DNA/RNA bases

Matias Berdakin, Géraldine Féraud, Claude Dedonder-Lardeux, Christophe Jouvet, Gustavo A. Pino

2014-03-28 Paper

DOI: 10.1039/C4CP00742E

On the scaling behavior of electric conductivity in [C4mim][NTf2]

J. Pionteck, J. Jacquemin

2014-08-12 Paper

DOI: 10.1039/C4CP02253J

Inside front cover

2022-03-15 Cover

DOI: 10.1039/C4CP90135E

A DFT study on the reaction mechanism of dimerization of methyl methacrylate catalyzed by N-heterocyclic carbene

Yunxia Li, Yanyan Zhu, Wenjing Zhang, Donghui Wei, Yingying Ran, Qilin Zhao, Mingsheng Tang

2014-07-31 Paper

DOI: 10.1039/C4CP02186J

Anomalous high adsorption energy of H2O on fluorinated graphenes: a first principles study

Peng Wang, Hongtao Wang, Wei Yang

2014-08-12 Paper

DOI: 10.1039/C4CP01784F

Contents list

Front/Back Matter

DOI: 10.1039/C4CP90059F

You might also like

Compound Q&A

Is 4-Benzyl-2,2-dimethylmorpholine (CAS: 84761-04-6) safe?

4-Benzyl-2,2-dimethylmorpholine is generally considered safe when handled under ...

84761-04-64-Benzyl-2,2-dimethy...
Compound Q&A

What is (5,6-Dimethoxy-3-pyridinyl)boronic acid (CAS: 1346526-61-1)?

(5,6-Dimethoxy-3-pyridinyl)boronic acid is a chemical compound with the molecula...

1346526-61-1(5,6-Dimethoxy-3-pyr...
Compound Q&A

How is 1,1,3,3-Tetramethyl-1,3-bis(2-methyl-2-propanyl)disiloxane (CAS: 67875-55-2) typically synthesized?

1,1,3,3-Tetramethyl-1,3-bis(2-methyl-2-propanyl)disiloxane is synthesized throug...

67875-55-21,1,3,3-Tetramethyl-...
Compound Q&A

What are the main uses of (2R,4S)-1-Boc-4-methylpyrrolidine-2-carboxylic acid (CAS: 1018818-04-6)?

(2R,4S)-1-Boc-4-methylpyrrolidine-2-carboxylic acid is primarily used as a build...

1018818-04-6(2R,4S)-1-Boc-4-meth...
Compound Q&A

What precautions should be taken when handling 2,3-Dichloroacrylonitrile (CAS: 22410-58-8)?

When handling 2,3-Dichloroacrylonitrile, it is crucial to wear appropriate perso...

22410-58-82,3-Dichloroacryloni...
Compound Q&A

How should (S)-1-(o-Tolyl)ethanamine hydrochloride (CAS: 1332832-16-2) be stored?

(S)-1-(o-Tolyl)ethanamine hydrochloride should be stored in a cool, dry place to...

1332832-16-2(S)-1-(o-Tolyl)ethan...
Compound Q&A

What are the physical and chemical properties of Benzyl [1-(hydroxyamino)-1-imino-2-methyl-2-propanyl]carbamate (CAS: 518047-98-8)?

Benzyl [1-(hydroxyamino)-1-imino-2-methyl-2-propanyl]carbamate (CAS: 518047-98-8...

518047-98-8Benzyl [1-(hydroxyam...
Compound Q&A

What industries use 2-Methyloxazole-5-carbaldehyde (CAS: 885273-42-7)?

2-Methyloxazole-5-carbaldehyde is used in the pharmaceutical industry for the sy...

885273-42-72-Methyloxazole-5-ca...
Compound Q&A

What is the market or research trend for 2-Methyl-2-propanyl 4-[(1S)-1-hydroxyethyl]-1-piperidinecarboxylate (CAS: 389889-82-1)?

The market for 2-Methyl-2-propanyl 4-[(1S)-1-hydroxyethyl]-1-piperidinecarboxyla...

389889-82-12-Methyl-2-propanyl ...
Compound Q&A

Is 1-Butyl-3-methylpyridinium bromide (CAS: 26576-85-2) safe?

1-Butyl-3-methylpyridinium bromide is generally considered safe for laboratory u...

26576-85-21-Butyl-3-methylpyri...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.