On the scaling behavior of electric conductivity in [C4mim][NTf2]
Literature Information
J. Pionteck, J. Jacquemin
In this work we examine, for the first time, the molar conductivity behavior of the deeply supercooled room temperature ionic liquid [C4mim][NTf2] in the temperature, pressure and volume thermodynamic space in terms of density scaling (TVγ)−1 combined with the equation of state (EOS). The exponent γσ determined from the Avramov model analysis is compared with the coefficient obtained from the viscosity studies carried out at moderate temperatures. Therefore, the experimental results presented herein provide the answer to the long-standing question regarding the validity of thermodynamic scaling of ionic liquids over a wide temperature range, i.e. from the normal liquid state to the glass transition point. Finally, we investigate the relationship between the dynamic and thermodynamic properties of [C4mim][NTf2] represented by scaling exponent γ and Grüneisen constant γG, respectively.
Related Literature
Boronic acid based imprinted electrochemical sensor for rutin recognition and detection
Chunlei Wang, Qi Wang, Min Zhong, Xianwen Kan
DOI: 10.1039/C6AN01294A
Integrated on-chip mass spectrometry reaction monitoring in microfluidic devices containing porous polymer monolithic columns
C. Dietze, S. Schulze, S. Ohla, K. Gilmore, P. H. Seeberger, D. Belder
DOI: 10.1039/C6AN01467D
Recent topics on single-molecule fluctuation analysis using blinking in surface-enhanced resonance Raman scattering: clarification by the electromagnetic mechanism
Tamitake Itoh
DOI: 10.1039/C6AN00936K
Highly stable SERS pH nanoprobes produced by co-solvent controlled AuNP aggregation
DOI: 10.1039/C6AN00650G
Sensitive detection of acid phosphatase based on graphene quantum dots nanoassembly
Weidan Na, Tianyu Hu, Xingguang Su
DOI: 10.1039/C6AN01087C
Enzymatic conversion of magnetic nanoparticles to a non-magnetic precipitate: a new approach to magnetic sensing
Arati G. Kolhatkar, Andrew C. Jamison, Ivan Nekrashevich, Katerina Kourentzi, Audrius Brazdeikis, T. Randall Lee
DOI: 10.1039/C6AN00709K
Visualization of exhaled hydrogen sulphide on test paper with an ultrasensitive and time-gated luminescent probe
Jianping Wang, Guangmei Han, Guijian Guan
DOI: 10.1039/C6AN00830E
Investigating non-specific binding to chemically engineered sensor surfaces using liposomes as models
C. Fenzl, C. Genslein, C. Domonkos, K. A. Edwards, T. Hirsch
DOI: 10.1039/C6AN00820H
Pseudo isobaric peptide termini labelling for relative proteome quantification by SWATH MS acquisition
Yichu Shan, Zhigang Sui, Qi Wu, Lihua Zhang, Zhen Liang, Yukui Zhang
DOI: 10.1039/C6AN00388E
You might also like
What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?
When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...
What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?
4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...
How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?
Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...
What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?
(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...
What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?
2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...
Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?
There are alternative reagents that can be used in synthesis instead of (E)-4-(t...
What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?
[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...
What is the market or research trend for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]{[(4-methylphenyl)sulfonyl]oxy}acetate (CAS: 166249-17-8)?
The market and research trends for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4...
What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?
The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...
What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?
4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![6-Nitro-2-(4-nitrophenyl)imidazo[1,2-a]pyridine structure 6-Nitro-2-(4-nitrophenyl)imidazo[1,2-a]pyridine structure](https://static.chemtradehub.com/structs/118/118000-57-0-cb82.webp)
![4-[2-(3,4-Dihydro-2H-chromen-6-yl)-1,3-oxazol-5-yl]-1-(3-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}benzyl)pyridinium bromide structure 4-[2-(3,4-Dihydro-2H-chromen-6-yl)-1,3-oxazol-5-yl]-1-(3-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}benzyl)pyridinium bromide structure](https://static.chemtradehub.com/structs/155/155863-03-9-8183.webp)