Copolymerisation of 1-alkenes with bulky oxygen-containing olefins for dual-stage functionalisation of polyolefins
Literature Information
Publication Date
2020-11-18
DOI
10.1039/D0PY01303J
Impact Factor
5.582
Authors
Makoto Nakamura, Kohtaro Osakada
View Original
Abstract
Pd–Diimine complexes catalyse the copolymerisation of 1-alkenes with olefins having a bulky oxygen-containing substituent, either 4-methyl-1-vinyl-2,6,7-trioxabicyclo[2.2.2]octane (VTO) or 2-methyl-2-vinyl-1,3-dioxolane (MVD), to afford a copolymer containing functional groups (up to 34 mol% of the total repeating units). The repeating units from VTO and MVD are mainly incorporated into the terminal of the branches and the main chain of the copolymer, respectively. Hydrolysis of the resulting copolymers by CF3COOH affords polymers with COOH or COMe substituents, which are difficult to obtain efficiently by the direct copolymerisation of acrylic acid or methyl vinyl ketone.
Related Literature
Enhancing the ionic conductivity and mechanical properties of PEO-based solid electrolytes through thermal pre-stretching treatment
Hong Liu
2023-06-19
Paper
DOI: 10.1039/D3CP01068F
Surface-sealing encapsulation of phosphotungstic acid in microporous UiO-66 as a bifunctional catalyst for transfer hydrogenation of levulinic acid to γ-valerolactone
Siteng Rong, Zhiyuan Zong, Pengrui Zhang, Rongrong Zhao, Feng Song, Hongyou Cui, Zhe-Ning Chen, Weiming Yi, Fengshan Zhang
2023-06-30
Paper
DOI: 10.1039/D3CP00727H
Calcium selective test strip for water and milk
L. F. Capitán-Vallvey, M. D. Fernández-Ramos, P. Álvarez de Cienfuegos Gálvez, F. Santoyo-González
2004-06-25
Paper
DOI: 10.1039/B403231D
A first-principles study of the structural, electronic and elastic properties of the FeO2–FeO2He system under high pressure
Haibo Liu, Lei Liu, Cunlin Xin, Longxing Yang, Xiaoyu Gu
2023-07-11
Paper
DOI: 10.1039/D3CP02315J
Thermal stability of azole-rich energetic compounds: their structure, density, enthalpy of formation and energetic properties
Xiangyan Miao, Xinbo Yang, Yuchuan Li, Siping Pang
2023-06-22
Review Article
DOI: 10.1039/D3CP02121A
Human-centric intelligent systems for exploration and knowledge discovery
2004-12-01
Forum
DOI: 10.1039/B307211H
Recent advances in encapsulation of highly stable perovskite nanocrystals and their potential applications in optoelectronic devices
Zhengwei Cao, Feng Zhang, Jiaqi Liu, Cuihe Fan, Yukun Wu, Yuying Hao
2023-06-08
Review Article
DOI: 10.1039/D3CP00941F
Screening of specific antigens for SARS clinical diagnosis using a protein microarray
Dan-Dan Lu, Su-Hong Chen, Shi-Meng Zhang, Min-Li Zhang, Wei Zhang, Xiao-Chen Bo, Sheng-Qi Wang
2005-02-14
Paper
DOI: 10.1039/B415888A
You might also like
Compound Q&A
What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?
1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...
141290-59-71H-Indazole-6-carbon...
Compound Q&A
How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?
Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...
2997-85-5Dioctyl (2E)-2-buten...
Compound Q&A
What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?
Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...
68291-98-5Sodium [(1,2-benzoxa...
Compound Q&A
Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?
Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...
741709-66-0Dimethyl 4-(4,4,5,5-...
Compound Q&A
How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?
Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...
80714-39-22-Fluoro-6-hydrazino...
Compound Q&A
What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?
6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...
499214-11-86-Formyl-2-pyridinec...
Compound Q&A
What is the market or research trend for 3-(3,4-dimethoxyphenyl)-2,5-dimethyl-N-(2-morpholin-4-ylethyl)pyrazolo[1,5-a]pyrimidin-7-amine (CAS: 900874-91-1)?
Research trends for this compound indicate a focus on its potential applications...
900874-91-13-(3,4-dimethoxyphen...
Compound Q&A
How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?
9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...
29875-73-89H-Tribenzo[b,d,f]az...
Compound Q&A
How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?
1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...
1797982-51-41-Cyclopropyl-7-etho...
Compound Q&A
How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?
Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...
671820-52-3Methyl 3-oxo-1,2,3,4...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![N-[(9H-Fluoren-9-ylmethoxy)carbonyl]serine structure](https://static.chemtradehub.com/structs/737/73724-45-5-b0dc.webp "N-[(9H-Fluoren-9-ylmethoxy)carbonyl]serine structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.