Tellurophene-containing π-conjugated polymers with unique heteroatom–heteroatom interactions by post-element-transformation of an organotitanium polymer
Literature Information
Publication Date
2020-07-07
DOI
10.1039/D0PY00724B
Impact Factor
5.582
Authors
Hiroki Nishiyama, Feng Zheng, Shinsuke Inagi, Hiroyuki Fueno, Ikuyoshi Tomita
View Original
Abstract
A unique π-conjugated polymer that possesses fully coplanar ring units through a tellurium–oxygen interaction, poly[(tellurophene-2,5-diyl)-alt-(2,5-dialkoxybenzene-1,4-diyl)], was prepared by the post-element-transformation of a titanacyclopentadiene-containing reactive precursor. The characteristic features of the heteroatom–heteroatom interaction and the electronic features of the polymer such as high HOMO and low LUMO energy levels are described.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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