Switching from an electride-like molecule to the molecular electride K-F6C6H6 driven by an oriented external electric field
Literature Information
Yin-Feng Wang, Tian Qin, Jia-Jun Wang, Xue-Xia Liu, Zhi-Jun Wang, Jiangen Huang, Jia Li, Zhi-Ru Li
The exploration of innovative molecular switches has resulted in large developments in the field of molecular electronics. Focusing on a single molecular switch with different forms exhibiting different electride features, potassium-atom-doped all-cis 1,2,3,4,5,6-hexafluorocyclohexane K-F6C6H6 was studied theoretically. It was found that an oriented external electric field can drive excess electron transfer from the region outside of the K atom to that outside of F6C6H6. Subsequently, the electride-like molecule K-F6C6H6 (1) switches into the molecular electride K-F6C6H6⋯e− (3) through another electride-like molecule K-F6C6H6 (2). The static first hyperpolarizabilities (β0) are increased over 12- and 5-fold when moving from 1 to 2 and 3, respectively. The rise of each β0 value constitutes an order of magnitude improvement. Between them, the different β0 values suggest that K-F6C6H6 is a good candidate for use as a multiple-response nonlinear optics switch. The order of the β0 values of 1–4 for M-F6C6H6 (M = Li and Na) coincide with that of K-F6C6H6, also exhibiting a switch effect.
Related Literature
Direct measurements of xanthine in 2000-fold diluted xanthinuric urine with a nanoporous carbon fiber sensor
Mehjabin Kathiwala, Andrews Obeng Affum, Jason Perry, Anna Brajter-Toth
DOI: 10.1039/B718125F
Integrated strong cation exchange/capillary reversed-phase liquid chromatography/on-target digestion coupled with mass spectrometry for identification of intact human liver tissue proteins‡
Mingxia Gao, Wenjia Yu, Yang Zhang, Guoquan Yan, Chunhui Deng, Xiangmin Zhang
DOI: 10.1039/B803388A
Imprinted polymers for chiral resolution of (±)-ephedrine. Part 2: probing pre-polymerisation equilibria in different solvents by NMR‡
Richard J. Ansell, Dongyao Wang, Janice K. L. Kuah
DOI: 10.1039/B806376A
Electronic integrated multisensor tongue applied to grape juice and wine analysis
Lia Moreno i Codinachs, Antoni Baldi, Andrey Ipatov, Andrey Bratov, Cecilia Jiménez-Jorquera
DOI: 10.1039/B801228H
Use of the thyrocyte sodium iodide symporter as the basis for a perchlorate cell-based assay
Irene E. MacAllister, Michael G. Jakoby IV, Bruce Geryk, Roger L. Schneider, Donald M. Cropek
DOI: 10.1039/B802710B
Novel fluorescence enhancement IgE assay using a DNA aptamer
Jing-Lin He, Zai-Sheng Wu, Song-Bai Zhang, Guo-Li Shen, Ru-Qin Yu
DOI: 10.1039/B812450G
Viral detection using DNA functionalized gold filaments
Jonas W. Perez, Frederick R. Haselton, David W. Wright
DOI: 10.1039/B904191E
Electrode array detector for microchip capillary electrophoresis
Ryan E. Holcomb, James R. Kraly, Charles S. Henry
DOI: 10.1039/B816289A
You might also like
Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?
When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...
How should (1R,9S,10S,12S,14E,16S,19R,20R,21S,22R)-3,9,21-Trihydroxy-5,10,12,14,16,20,22-heptamethyl-23,24-dioxatetracyclo[17.3.1.1~6,9~.0~2,7~]tetracosa-2,5,7,14-tetraen-4-one (CAS: 183202-73-5) be stored?
This compound should be stored in a cool, dry place away from direct sunlight. I...
How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?
3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...
How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?
5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...
What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?
2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...
What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?
3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...
Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?
Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...
Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?
Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...
What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?
3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...
What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?
When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![[4-(Isobutyrylamino)phenyl]boronic acid structure [4-(Isobutyrylamino)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/874/874219-50-8-6ab5.webp)



