Temperature control in DRIFT cells used for in situ and operando studies: where do we stand today?

Literature Information

Publication Date 2020-10-26
DOI 10.1039/D0CP04352D
Impact Factor 3.676
Authors

Ignacio Melián-Cabrera


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Abstract

Vibrational spectroscopy is considered a workhorse in heterogeneous catalysis. This group of techniques has allowed an understanding of the structure of the solid catalysts, not only with ex situ methodologies but also with in situ and operando studies. In this perspective, an appraisal of diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) is provided, in particular regarding the heat transfer limitations in the cell, and solutions, which can affect the measurement, with consequences in kinetic studies.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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