Unsaturated binuclear homoleptic nickel carbonyl anions Ni2(CO)n− (n = 4–6) featuring double three-center two-electron Ni–C–Ni bonds
Literature Information
Zhiling Liu, Yan Bai, Ya Li, Jing He, Qingyang Lin, Hua Xie, Zichao Tang
The homoleptic homodinuclear nickel carbonyl anions Ni2(CO)n− (n = 4–6) are mass-selected in the gas phase and examined with anion photoelectron velocity-map imaging spectroscopy combined with density functional calculations. The doubly carbonyl-bridged structures are found to be favorable for Ni2(CO)n− (n = 4–6). The nature of Ni–Ni bonding in these complexes is analysed with the aid of a range of state-of-the-art quantum chemistry methods. Despite the absence of direct multiple Ni–Ni bonds, the two nickel atoms in Ni2(CO)n− (n = 4–6) complexes are joined by two bridging carbonyl ligands via the sharing three-center two-electron Ni–C–Ni bond in turn to achieve the (16,16), (16,18), and eventually the favored (18,18) configurations.
Recommended Journals
Related Literature
Polyester-graft-phosphorylcholine prepared by ring-opening polymerization and click chemistry
Beth M. Cooper, Delphine Chan-Seng, Debasis Samanta, Xiongfei Zhang, Sangram Parelkar, Todd Emrick
DOI: 10.1039/B817600K
Monoalkylation of primary amines and N-sulfinylamides
José Luis García Ruano, Alejandro Parra, José Alemán, Francisco Yuste, Virginia M. Mastranzo
DOI: 10.1039/B816846F
Fluorophore-cored dendrimers for patterns in metalloprotein sensing
Siriporn Jiwpanich, Britto S. Sandanaraj, S. Thayumanavan
DOI: 10.1039/B815263B
Chemistry and structural determination of botcinolides, botcinins, and botcinic acids
Isamu Shiina, Hiroki Fukui
DOI: 10.1039/B814375G
Microwave synthesis of Cr nanowires on polymeric substrate
Daeseob Shim, Seung-Ho Jung, Eun-Ha Kim, Dong-Myung Yoon, Kun-Hong Lee, Soo-Hwan Jeong
DOI: 10.1039/B816534C
3-Mercaptopropionic acid-mediated synthesis of peptide and protein thioesters
Jaskiranjit Kang, Jonathan P. Richardson, Derek Macmillan
DOI: 10.1039/B815888F
Solid-phase based total synthesis of Jasplakinolide by ring-closing metathesis
Tai-Shan Hu
DOI: 10.1039/B900342H
Reversible increase in the redox potential of cytochrome c in methanol
Suzanne Crilly, Edmond Magner
DOI: 10.1039/B819618D
Photolysis of diarylvinylcyclopropenes for the construction of 1-methylene-8a-aryl-1,8a-dihydroazulene skeletons
Fang-Fang Yu, Wang-Gui Yang
DOI: 10.1039/B820212E
You might also like
What are the main uses of (5-Sulfamoyl-3-pyridinyl)boronic acid (CAS: 951233-61-7)?
(5-Sulfamoyl-3-pyridinyl)boronic acid is primarily used in chemical synthesis, p...
How is Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate (CAS: 1942858-50-5) typically synthesized?
Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate is typically synthesized via est...
What precautions should be taken when handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0)?
When handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0), it is important to use p...
What are the physical and chemical properties of 1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2)?
1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2) is a crystalline c...
What industries use Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carboxylate (CAS: 174726-87-5)?
Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carbox...
What precautions should be taken when handling Delta-7-Avenasterol (CAS: 23290-26-8)?
When handling Delta-7-Avenasterol (CAS: 23290-26-8), it is important to wear app...
What precautions should be taken when handling N-({(5R)-3-[3-Fluoro-4-(4-morpholinyl)phenyl]-2-oxo-1,3-oxazolidin-5-yl}methyl)acetamide (CAS: 872992-20-6)?
Proper handling involves the use of personal protective equipment such as gloves...
What precautions should be taken when handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylate (CAS: 79099-00-6)?
When handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylat...
What is N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7)?
N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7) is a organic compou...
Is [2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) safe?
[2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) is generally considered safe...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












![2-Azaspiro[4.5]decane-3,8-dione structure 2-Azaspiro[4.5]decane-3,8-dione structure](https://static.chemtradehub.com/structs/914/914780-96-4-e94b.webp)
![N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure](https://static.chemtradehub.com/structs/122/1227374-64-2-cdb5.webp)
