Photolysis of diarylvinylcyclopropenes for the construction of 1-methylene-8a-aryl-1,8a-dihydroazulene skeletons

Literature Information

Publication Date 2009-02-11
DOI 10.1039/B820212E
Impact Factor 6.222
Authors

Fang-Fang Yu, Wang-Gui Yang


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Abstract

Photoirradiation of vinylcyclopropenes 1 in a Pyrex tube provides 1-isopropylidene-3,8a-diphenyl-1,8a-dihydroazulene derivatives 2 in moderate to good yields within 4.5–14 h. A plausible mechanism has been discussed for the formation of these interesting products.

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