Reversible increase in the redox potential of cytochrome c in methanol

Literature Information

Publication Date 2008-12-19
DOI 10.1039/B819618D
Impact Factor 6.222
Authors

Suzanne Crilly, Edmond Magner


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Abstract

The E°′ of cytochrome c on a self-assembled monolayer (SAM) modified gold electrode increased by 300 mV immediately on immersion in methanol; on re-immersion of the electrode in aqueous buffer, the original faradaic response was restored, but over a period of 120 min, indicating that methanol causes a significant change in conformation/orientation of the protein.

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