![N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure](https://static.chemtradehub.com/structs/122/1227374-64-2-cdb5.webp "N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure")
N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide
CAS Number:
1227374-64-2
Molecular Formula:
C49H37F3NO5PS
Rational synthesis of Pt-based dandelion-like yolk–shell nanoparticles with enhanced oxygen reduction properties
Literature Information
Publication Date
2019-09-09
DOI
10.1039/C9SE00618D
Impact Factor
6.367
Authors
Chunjie Li, Shuli Yin, Hongjie Yu, Ziqiang Wang, You Xu, Xiaonian Li, Liang Wang, Hongjing Wang
View Original
Abstract
The regulation of the composition and architecture of Pt-based noble metal materials is significantly important for the preparation of high-performance oxygen reduction electrocatalysts. In this work, Pd@PtPd dandelion-like yolk–shell nanoparticles (Pd@PtPd DYSNs) were rationally fabricated by a simple template method. On account of the unique structure and the admirable match of Pt and Pd, the prepared Pd@PtPd DYSNs exhibit dramatically enhanced oxygen reduction activity and stability compared with PtPd dandelion-like hollow nanoparticles (PtPd DHNs) and commercial Pt/C. The present synthetic strategy contributes to lowering cost and improving catalytic performance, which is of great significance for the development of Pt-based catalysts with advanced properties.
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