Metal-free iminyl radical-mediated C–C single bond cleavage/functionalization of redox-active oxime esters
Literature Information
Publication Date
2020-01-13
DOI
10.1039/C9QO01446B
Impact Factor
5.281
Authors
Miao-Miao Zhang, Shi-Hong Li, Jia-Lin Tu, Qing-Qiang Min, Feng Liu
View Original
Abstract
A visible-light-driven iminyl radical-mediated C–C bond cleavage and functionalization of cycloketone oxime esters have been accomplished. This protocol is simple and does not require expensive and toxic photoredox and/or transition-metal catalysis, providing a novel catalyst-free strategy for alkylation, allylation, vinylation and alkynylation through addition of C(sp3)-centered radicals to various unsaturated acceptors. The commercially available and photoactive Hantzsch ester effectively serves as an electron donor, as well as a hydrogen atom source.
Related Literature
Optimal design of thiostrepton-derived thiopeptide antibiotics and their potential application against oral pathogens
Jian Wang, Xuebing Bai, Jiang Tao
2019-02-28
Research Article
DOI: 10.1039/C9QO00219G
Mechanical generation of isocyanate by mechanically induced retro [2 + 2] cycloaddition of a 1,2-diazetidinone mechanophore
Yangju Lin, Chia-Chih Chang, Stephen L. Craig
2019-03-15
Research Article
DOI: 10.1039/C9QO00262F
Supramolecularly assisted synthesis of chiral tripodal imidazolium compounds‡
Adriana Valls, Belén Altava, M. Isabel Burguete, Jorge Escorihuela, Vicente Martí-Centelles, Santiago V. Luis
2019-03-04
Research Article
DOI: 10.1039/C9QO00163H
Progress in the synthesis of perylene bisimide dyes
Agnieszka Nowak-Król, Frank Würthner
2019-03-07
Review Article
DOI: 10.1039/C8QO01368C
n-Butyllithium catalyzed hydroboration of imines and alkynes
Dandan Yan, Xueli Wu, Jian Xiao, Zhangye Zhu, Xiaojuan Xu, Xiaoguang Bao, Yingming Yao, Qi Shen, Mingqiang Xue
2019-01-15
Research Article
DOI: 10.1039/C8QO01289J
A l-glutamate-responsive delivery system based on enzyme-controlled self-immolative arylboronate-gated nanoparticles
Reynaldo Villalonga
2019-03-12
Research Article
DOI: 10.1039/C9QO00093C
Reductive cleavage of the N–O bond: elemental sulfur-mediated conversion of N-alkoxyamides to amides
Senlin Wang, Xue Zhao, Daisy Zhang-Negrerie
2018-12-14
Research Article
DOI: 10.1039/C8QO01052H
Enantioselective synthesis of trifluoromethylated dihydroquinoxalinones via palladium-catalyzed hydrogenation
Zhihong Deng, Qin Yang, Jian Huang, Yiyuan Peng
2019-01-31
Research Article
DOI: 10.1039/C8QO01361F
Encapsulation of dihydrogenphosphate ions as a cyclic dimer to the cavities of site-specifically modified indolocarbazole-pyridine foldamers‡
Chaeeun Lee, Hyemi Lee, Seungwon Lee, Hae-Geun Jeon, Kyu-Sung Jeong
2018-12-28
Research Article
DOI: 10.1039/C8QO01307A
You might also like
Compound Q&A
How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?
Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...
100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A
How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?
7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...
1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A
What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?
2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...
124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A
Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?
1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...
1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A
What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?
The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...
113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A
What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?
3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...
163271-80-53-(Triisopropylsilyl...
Compound Q&A
What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?
6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...
81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A
How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?
Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...
885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A
What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?
N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...
55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A
What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?
6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...
1036756-15-66-Bromo-8-fluoro-2-q...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![N-[(E)-Phenylmethylene]benzenesulfonamide structure](https://static.chemtradehub.com/structs/139/13909-34-7-8167.webp "N-[(E)-Phenylmethylene]benzenesulfonamide structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.