Copper-promoted dehydrogenative cross-coupling reaction of dialkyl phosphites with sulfoximines

Literature Information

Publication Date 2019-05-06
DOI 10.1039/C9QO00469F
Impact Factor 5.281
Authors

Surabhi Gupta, Siddharth Baranwal, Priyanka Chaudhary, Jeyakumar Kandasamy


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Abstract

An efficient method for the dehydrogenative cross-coupling of dialkyl phosphites with sulfoximines is demonstrated in the presence of copper(II) acetate and triethylamine. A library of sulfoximines including aryl, heteroaryl and alkyl sulfoximines underwent coupling reaction smoothly and gave the desired sulfoximine derived phosphoramidates in good to excellent yields.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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