Orthogonally arranged tripyrrin–BODIPY conjugates with an “edge to plane” mode

Literature Information

Publication Date 2019-04-25
DOI 10.1039/C9QO00445A
Impact Factor 5.281
Authors

Chun-Liang Hou, Yuhang Yao, Da Wang, Jing Zhang, Jun-Long Zhang


View Original

Abstract

We designed new molecular conjugates, consisting of two strong fluorophores, tripyrrin and BODIPY moieties. Crystal structures demonstrated that the BODIPY is nearly perpendicular to the tripyrrin plane, directly linked in an orthogonal geometry, in a new “edge to plane” mode with covalently bonded chromophore peripheries. Furthermore, substitutions on BODIPY can modulate the photophysical properties, which can be explained by energy transfer via a FRET mechanism. This not only enriches the repertoire of multichromophoric system but also expands the scope of tripyrrin for constructing molecular functional materials.

Related Literature

Inside back cover

Cover

DOI: 10.1039/C2PY90015G

Poly(vinylidene fluoride)-functionalized single-walled carbon nanotubes for the preparation of composites with improved conductivity

Radovan Vukićević, Ivana Vukovic, Hristiyan Stoyanov, Andreas Korwitz, Doris Pospiech, Guggi Kofod, Katja Loos, Gerrit ten Brinke, Sabine Beuermann

2012-05-16 Paper

DOI: 10.1039/C2PY20166F

Contents list

2021-02-24 Front/Back Matter

DOI: 10.1039/C2PY90002E

Spectroscopic study of side-chain melting and crystallization of regioregular poly(3-dodecylthiophene)

Yan Guo, Ying Jin, Zhaohui Su

2012-02-03 Communication

DOI: 10.1039/C2PY00582D

Polymeric vesicles mimicking glycocalyx (PV-Gx) for studying carbohydrate–protein interactions in solution

Lu Su, Yu Zhao, Guosong Chen, Ming Jiang

2012-04-13 Paper

DOI: 10.1039/C2PY20110K

Glycopolymer–peptidebioconjugates with antioxidant activity via RAFT polymerization

Haiting Shi, Li Liu, Xiaobei Wang, Jingyi Li

2012-02-29 Paper

DOI: 10.1039/C2PY20021J

Double modular modification of thiolactone-containing polymers: towards polythiols and derived structures

Pieter Espeel, Fabienne Goethals, Milan M. Stamenović, Lionel Petton, Filip E. Du Prez

2012-02-03 Paper

DOI: 10.1039/C2PY00565D

Functional block copolymernanoparticles: toward the next generation of delivery vehicles

Maxwell J. Robb, Luke A. Connal, Bongjae F. Lee, Nathaniel A. Lynd

2012-04-18 Paper

DOI: 10.1039/C2PY20131C

You might also like

Compound Q&A

Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?

When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...

3848-36-01-(4-Chlorophenyl)-N...
Compound Q&A

How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?

3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...

419553-16-53-(4-Bromophenyl)-5-...
Compound Q&A

How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?

5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...

1639220-19-15-Chloro-2-(4-chloro...
Compound Q&A

What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?

2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...

1206978-15-52-Chloro-4-(difluoro...
Compound Q&A

What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?

3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...

1121-79-53-Chloro-6-methylpyr...
Compound Q&A

Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?

Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...

90922-74-0Methyl 4,5-dimethyl-...
Compound Q&A

Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?

Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...

63405-68-5(2E,2'E)-3,3'-(1,4-P...
Compound Q&A

What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?

3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...

1261906-29-93-Amino-5-chloropyri...
Compound Q&A

What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?

When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...

1092349-93-36,7-Difluoro-2,3-dih...

Source Journal

Organic Chemistry Frontiers

Organic Chemistry Frontiers
CiteScore: 7.8
Self-citation Rate: 8.7%
Articles per Year: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.