Poly(vinylidene fluoride)-functionalized single-walled carbon nanotubes for the preparation of composites with improved conductivity

Literature Information

Publication Date 2012-05-16
DOI 10.1039/C2PY20166F
Impact Factor 5.582
Authors

Radovan Vukićević, Ivana Vukovic, Hristiyan Stoyanov, Andreas Korwitz, Doris Pospiech, Guggi Kofod, Katja Loos, Gerrit ten Brinke, Sabine Beuermann


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Abstract

The surface of single-walled carbon nanotubes (SWCNTs) was functionalized with azide-terminated poly(vinylidene fluoride) (PVDF). Functionalization was confirmed by dispersibility, Raman spectroscopy, and thermogravimetric analyses. Raman spectra show disordering of the SWCNTs, thus, strongly suggesting that PVDF was covalently attached to SWCNTs. Functionalized SWCNTs were mixed with commercially available PVDF in a twin-screw extruder and thin films were obtained by melt-pressing. Films containing 0.5 and 1 wt% PVDF-functionalized SWCNTs exhibited significantly improved electrical conductivity compared to PVDF films containing pristine SWCNTs.

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