Palladium-catalyzed diastereo- and enantioselective formal [3 + 2] cycloaddition of vinyl cyclopropanes with cyclic 1-azadienes
Literature Information
Qing Zhou, Bo Chen, Xiao-Bing Huang, Ya-Li Zeng, Wen-Dao Chu, Quan-Zhong Liu
Palladium-catalyzed asymmetric formal [3 + 2] cycloadditions of vinyl cyclopropanes and cyclic 1-azadienes proceeded smoothly in the presence of chiral phosphoramidite ligands to afford the corresponding highly functionalized cyclopentanes in good yields along with high enantioselectivities under mild conditions.
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