Photoredox-catalyzed sulfonylation of alkenylcyclobutanols with the insertion of sulfur dioxide through semipinacol rearrangement
Literature Information
Publication Date
2019-04-11
DOI
10.1039/C9QO00300B
Impact Factor
5.281
Authors
Fu-Sheng He, Youqian Wu, Xiaofang Li, Hongguang Xia
View Original
Abstract
A photoredox-catalyzed sulfonylation of alkenylcyclobutanols with the insertion of sulfur dioxide through semipinacol rearrangement under visible light irradiation is developed. This protocol provides an efficient and facile route to β-sulfonated ketones bearing α-carbon quaternary centers under mild conditions, which features good functional group compatibility. Preliminary mechanistic investigation shows that an arylsulfonyl radical-induced 1,2-carbon migration process is involved.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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CAS Number:
740081-22-5
Molecular Formula:
C17H13ClFN3O3
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