Formates plus triazabicyclodecene (TBD): an efficient platform for non-gaseous carbonylation and unexpected hydrogenation
Literature Information
Publication Date
2019-03-08
DOI
10.1039/C9QO00028C
Impact Factor
5.281
Authors
Jinzhong Yao, Linlin Chen, Linfeng Hu, Xiaofang Li, Hongwei Zhou
View Original
Abstract
A highly efficient palladium-catalyzed TBD–formate system for carbonylation/hydrogenation was reported. Based on the obvious solvent effect and reasonable mechanism study, we achieved tunable carbonylation or hydrogenation. With the advantages of simple operation, mild conditions and storable reagents, this protocol should be of interest not only for synthetic scientists but also helpful for laboratory operators.
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Organic Chemistry Frontiers
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