![2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure](https://static.chemtradehub.com/structs/567/56718-70-8-f037.webp "2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure")
1,2-Amino alcohol-dependent Petasis allylboration for racemic and chiral homoallylamines
Literature Information
Publication Date
2019-01-30
DOI
10.1039/C8QO01428K
Impact Factor
5.281
Authors
Zi-Wei Lin, Yang Zhou, Zhen-Ni Zhao, Yan Zhao, Jun Liu, Yi-Yong Huang
View Original
Abstract
Petasis allylboration among an aldehyde, 1,2-amino alcohol and pinacolallylboronate has been successfully accomplished at room temperature without any catalysts. A proposed reaction pathway involving the allylboration of an in situ-generated imine through a six-membered chairlike transition state is suggested to understand the role of a positioned hydroxy group and the diastereoselective outcome.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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