Group 9 [Cp*MIII] complex-catalyzed C–H olefination of arenes in water at room temperature: a study on the catalytic activity
Literature Information
Publication Date
2019-02-12
DOI
10.1039/C8QO01407H
Impact Factor
5.281
Authors
Hailong Zhang, Zhongzhen Yang, Jinxing Liu, Xinling Yu, Qiantao Wang, Yong Wu
View Original
Abstract
Herein, we report our discovery of group 9 [Cp*MIII] complexes catalyzing the olefination of arenes in water at ambient temperature. The reaction afforded the desired products in moderate to good yields. Among the group 9 [Cp*MIII] complexes, [Cp*RhCl2]2 was found to be the most efficient catalyst in this reaction, with the highest catalytic activity, the best scalability, the best recyclability and the broadest substrate scope. Mechanistic investigation revealed that the C–H bond cleavage was most likely to be achieved through the concerted metalation–deprotonation (CMD).
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![2,4-Dichloro-6-isopropyl-5H-pyrrolo[3,4-d]pyrimidin-7(6H)-one structure](https://static.chemtradehub.com/structs/107/1079649-94-7-ad4a.webp "2,4-Dichloro-6-isopropyl-5H-pyrrolo[3,4-d]pyrimidin-7(6H)-one structure")
2,4-Dichloro-6-isopropyl-5H-pyrrolo[3,4-d]pyrimidin-7(6H)-one
CAS Number:
1079649-94-7
Molecular Formula:
C9H9Cl2N3O
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