![10-(1-Azabicyclo[2.2.2]oct-3-ylmethyl)-10H-phenothiazine structure](https://static.chemtradehub.com/structs/292/29216-28-2-1d81.webp "10-(1-Azabicyclo[2.2.2]oct-3-ylmethyl)-10H-phenothiazine structure")
10-(1-Azabicyclo[2.2.2]oct-3-ylmethyl)-10H-phenothiazine
CAS Number:
29216-28-2
Molecular Formula:
C20H22N2S
Cobalt(iii)-catalyzed C–H amidation of weakly coordinating sulfoxonium ylides and α-benzoylketene dithioacetals
Literature Information
Publication Date
2019-01-28
DOI
10.1039/C8QO01270A
Impact Factor
5.281
Authors
Qingqian Jia, Lingheng Kong
View Original
Abstract
Cobalt(III)-catalyzed C–H amidation of arenes has been realized under assistance of weakly coordinating carbonyl groups with 1,4,2-dioxazol-5-ones as the amidating reagents. Both sulfoxonium ylides and α-benzoylketene dithioacetals are viable arene substrates. The coupling system features high yield, broad substrate scope, and functional group tolerance, providing a series of functionalized sulfur-containing compounds.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
2-Methyl-2-propanyl 4-iodo-1-piperidinecarboxylate
CAS Number:
301673-14-3
Molecular Formula:
C10H18INO2
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