Solvent-tuned chemoselective carboazidation and diazidation of alkenes via iron catalysis
Literature Information
Publication Date
2018-12-27
DOI
10.1039/C8QO01142G
Impact Factor
5.281
Authors
Lei Xu, Jian Chen, Lingling Chu
View Original
Abstract
We have described Fe-catalyzed chemoselective oxidative carboazidation and diazidation of alkenes by employing CH2Cl2 as the chloromethyl source and TMSN3 as the azido source. For the synthesis, we have taken the advantage of solvent-controlled generation of C-based and N-based radicals, allowing the construction of molecularly diverse azido compounds from readily available starting materials through a simple operation.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
(2S,4R)-4-(3-Bromobenzyl)pyrrolidine-2-carboxylic acid hydrochloride
CAS Number:
1049734-10-2
Molecular Formula:
C12H15BrClNO2
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