Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines

Literature Information

Publication Date 2018-10-25
DOI 10.1039/C8QO00984H
Impact Factor 5.281
Authors

Xincheng Li, Boshun Wan


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Abstract

Ring-opening and cyclization of aziridines with aryl azides in the presence of TfOH has been developed. This strategy enables the construction of 6-(triflyloxy)quinoline cores by utilizing aziridine as a two-carbon surrogate. The introduction of a trifyl group at the 6-position of quinoline would allow further construction of carbon–carbon and carbon–heteroatom bonds in the cross-coupling reactions.

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