Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines
Literature Information
Publication Date
2018-10-25
DOI
10.1039/C8QO00984H
Impact Factor
5.281
Authors
Xincheng Li, Boshun Wan
View Original
Abstract
Ring-opening and cyclization of aziridines with aryl azides in the presence of TfOH has been developed. This strategy enables the construction of 6-(triflyloxy)quinoline cores by utilizing aziridine as a two-carbon surrogate. The introduction of a trifyl group at the 6-position of quinoline would allow further construction of carbon–carbon and carbon–heteroatom bonds in the cross-coupling reactions.
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Self-citation Rate:
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