Enhanced electrochemical performance and thermal stability of LiNi0.5Mn1.5O4 using an electrolyte with sulfolane

Literature Information

Publication Date 2015-03-25
DOI 10.1039/C5CP00799B
Impact Factor 3.676
Authors

Qian Zhang, Jia-Jia Chen, Xue-Yin Wang, Cheng Yang, Ming-Sen Zheng, Quan-Feng Dong


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Abstract

A sulfide-based SEI layer was formed on the surface of a LiNi0.5Mn1.5O4 cathode by using a sulfolane–carbonate mixed solvent electrolyte, which led to an improvement in the electrochemical performance. Moreover, the thermal stability of the LiNi0.5Mn1.5O4 cathode was also significantly improved in the presence of the SEI layer. ARC (Accelerating Rate Calorimetry) tests showed that the self-heating rate of the delithiated LiNi0.5Mn1.5O4 material in the sulfolane–carbonate electrolyte was suppressed.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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