Yb(NTf2)3/HFIP induced high isotacticity in atom transfer radical polymerization of methyl methacrylate
Literature Information
Publication Date
2018-08-31
DOI
10.1039/C8PY00953H
Impact Factor
5.582
Authors
Sebastian Schaubach, Xiao-Yan Wang, Jun-Fang Li, Xiu-Li Sun, Sunewang R. Wang, Yong Tang
View Original
Abstract
High triad isotacticity (mm = 69%) in copper/BOX mediated ATRP of MMA is achieved. The use of strong Lewis acid Yb(NTf2)3 (1.0–8.0 mol%) and HFIP as the solvent is the key for this isotactic stereocontrol. A dilute concentration and a relatively low temperature are beneficial for further improving the isotacticity.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
(2R,4R)-1-Boc-4-Aminopyrrolidine-2-carboxylic acid
CAS Number:
132622-98-1
Molecular Formula:
C10H18N2O4
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