Synthesis of oxindoles through trifluoromethylation of N-aryl acrylamides by photoredox catalysis

Literature Information

Publication Date 2018-08-22
DOI 10.1039/C8OB01922C
Impact Factor 3.876
Authors

Maojian Lu, Zhiji Liu, Jinwang Zhang, Yu Tian, Honggui Qin, Mingqiang Huang, Shirong Hu


View Original

Abstract

Mild and direct intramolecular oxidative aryltrifluoromethylations of activated alkenes have been established through visible light photocatalysis, affording a range of CF3-containing oxindoles or isoquinolinediones in the presence of an organic fluorophore-type photocatalyst 4CzIPN, oxygen and visible light irradiation under strong oxidant and transition metal free conditions. A variety of frequently encountered functional groups are well tolerated in this transformation.

Related Literature

Folded amphiphilic homopolymer micelles in water: uniform self-assembly beyond amphiphilic random copolymers

Yoshihiko Kimura, Makoto Ouchi, Takaya Terashima

2020-07-06 Paper

DOI: 10.1039/D0PY00685H

Mechanically robust and reprocessable imine exchange networks from modular polyester pre-polymers

Rachel L. Snyder, Claire A. L. Lidston, Guilhem X. De Hoe, Maria J. S. Parvulescu, Marc A. Hillmyer, Geoffrey W. Coates

2020-02-27 Paper

DOI: 10.1039/C9PY01957J

Divergence of polycondensation by a tandem reaction based on sequential conjugate substitutions

Keito Hagiwara

2020-07-08 Communication

DOI: 10.1039/D0PY00648C

Green-light photocleavable meso-methyl BODIPY building blocks for macromolecular chemistry

Paul Strasser, Pauline Stadler, Patrick Breiteneder, Günther Redhammer, Markus Himmelsbach, Oliver Brüggemann, Uwe Monkowius, Ian Teasdale

2021-11-16 Paper

DOI: 10.1039/D1PY01245B

One-pot synthesis of amphiphilic multiblock poly(2-oxazoline)s via para-fluoro-thiol click reactions

Tieshuai Zhao, Ben Drain, Gokhan Yilmaz, C. Remzi Becer

2021-09-20 Paper

DOI: 10.1039/D1PY00944C

Direct fluorination as a one-step ATRP initiator immobilization for convenient surface grafting of phenyl ring-containing substrates

Taijun He, Zhenyu Xing, Yixing Wang, Difeng Wu, Yang Liu, Xiangyang Liu

2020-07-31 Paper

DOI: 10.1039/D0PY00860E

Porous polycaprolactone and polycarbonate poly(urethane urea)s via emulsion templating: structures, properties, cell growth‡

Katya Kapilov-Buchman, Tslil Bialystocki, Danna Niezni, Luba Perry, Shulamit Levenberg, Michael S. Silverstein

2021-11-01 Paper

DOI: 10.1039/D1PY01106E

Highly efficient UV-Vis light activated three-component photoinitiators composed of tris(trimethylsilyl)silane for polymerization of acrylates

Alicja Balcerak, Dominika Kwiatkowska, Katarzyna Iwińska, Janina Kabatc

2020-07-23 Paper

DOI: 10.1039/D0PY00763C

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
CiteScore: 3.4
Self-citation Rate: 10.3%
Articles per Year: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.