X-Ray scattering and physicochemical studies of trialkylamine/carboxylic acid mixtures: nanoscale structure in pseudoprotic ionic liquids and related solutions

Literature Information

Publication Date 2018-06-25
DOI 10.1039/C8CP02854K
Impact Factor 3.676
Authors

Kevin G. Yager


View Original

Abstract

We report the results of X-ray scattering, physical, and spectroscopic measurements on a series of water-saturated trialkylamine/carboxylic acid mixtures. The results demonstrate the existence of well-defined nanoscale structures in bulk liquid mixtures at specific acid : amine ratios. These structures are analogous to those observed in ionic liquids but are driven by the formation of a hydrogen-bonded network rather than via inter-ion Coulomb forces. The results of the physical components of this study are closely analogous to prior observations on anhydrous, low molecular weight acid/amine mixtures, but this is to our knowledge the first time these observations have been augmented by the use of X-ray scattering. The results therefore bridge the gap between early work on amine/acid mixtures and recent studies of protic and pseudoprotic ionic liquids.

Related Literature

Cascaded multiple recycling amplifications for aptamer-based ultrasensitive fluorescence detection of protein biomarkers

Yao Qin, Daxiu Li, Ruo Yuan, Yun Xiang

2019-09-27 Paper

DOI: 10.1039/C9AN01674K

A fluorescent probe based on aggregation-induced emission for hydrogen sulfide-specific assaying in food and biological systems

Lingfeng Xu, Ling Ni, Lihe Sun, Fang Zeng, Shuizhu Wu

2019-09-27 Paper

DOI: 10.1039/C9AN01582E

Nano-analytical characterization of endogenous minerals in healthy placental tissue: mineral distribution, composition and ultrastructure

Elena Tsolaki, Louis Didierlaurent, Samuel Staubli, Robert Zboray, Antonia Neels, Dörthe Dietrich, Pius Manser, Lotus May Desbiolles, Sebastian Leschka, Simon Wildermuth, Sandro Lehner, Pascale Chavatte-Palmer, Wolfram Jochum, Peter Wick, Tina Bürki-Turnherr, Tina Fischer, René Hornung, Sergio Bertazzo

2019-10-02 Communication

DOI: 10.1039/C9AN01312A

A fully battery-powered inexpensive spectrophotometric system for high-sensitivity point-of-care analysis on a microfluidic chip

Maowei Dou, Juan Lopez, Misael Rios, Oscar Garcia, Chuan Xiao, Michael Eastman, XiuJun Li

2016-04-20 Paper

DOI: 10.1039/C6AN00370B

Fluorescence array-based sensing of nitroaromatics using conjugated polyelectrolytes

Yu Zong Chen

2016-05-03 Communication

DOI: 10.1039/C6AN00678G

Sensitive detection of polycyclic aromatic hydrocarbons with gold colloid coupled chloride ion SERS sensor

Xiaoyong Liao, You Li, Hongying Cao, Yishu Zhao, Daniel P. Cassidy

2019-10-04 Paper

DOI: 10.1039/C9AN01540J

Investigating the effect of Ag nanocube polydispersity on gap-mode SERS enhancement factors

Tyler J. Dill, Matthew J. Rozin, Eric R. Brown, Stephen Palani, Andrea R. Tao

2016-04-29 Paper

DOI: 10.1039/C6AN00212A

A two-photon fluorescent probe for bio-imaging of formaldehyde in living cells and tissues

Jun-Bin Li, Qian-Qian Wang, Lin Yuan, Yong-Xiang Wu, Xiao-Xiao Hu, Xiao-Bing Zhang, Weihong Tan

2016-04-14 Paper

DOI: 10.1039/C6AN00473C

Approaches towards molecular amplification for sensing

Sean Goggins, Christopher G. Frost

2016-04-14 Critical Review

DOI: 10.1039/C6AN00348F

You might also like

Compound Q&A

What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?

When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...

79206-94-34-(2-Furylmethyl)thi...
Compound Q&A

What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?

When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...

71320-77-94-Chloro-N-[2-(4-mor...
Compound Q&A

How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?

Waste containing this compound (CAS: 62921-74-8) should be handled according to ...

62921-74-82-[2-(2-Methoxyethox...
Compound Q&A

How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?

Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...

40056-18-6(S)-Methyl 2-amino-3...
166882-70-85-({4-[(2S,4R)-4-Hyd...
Compound Q&A

Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?

There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...

7312-27-8(2E)-3-(3,4-Dichloro...
Compound Q&A

How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?

Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...

925437-84-9Ethyl 6-(2-nitrophen...
Compound Q&A

How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?

Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...

18453-07-12-(1,3-Thiazol-2-yl)...
Compound Q&A

How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?

Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...

103440-54-6Methyl 5-iodo-2-meth...
Compound Q&A

How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?

5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...

1427399-34-55-Chloro[1,2,4]triaz...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.