X-Ray scattering and physicochemical studies of trialkylamine/carboxylic acid mixtures: nanoscale structure in pseudoprotic ionic liquids and related solutions
Literature Information
Kevin G. Yager
We report the results of X-ray scattering, physical, and spectroscopic measurements on a series of water-saturated trialkylamine/carboxylic acid mixtures. The results demonstrate the existence of well-defined nanoscale structures in bulk liquid mixtures at specific acid : amine ratios. These structures are analogous to those observed in ionic liquids but are driven by the formation of a hydrogen-bonded network rather than via inter-ion Coulomb forces. The results of the physical components of this study are closely analogous to prior observations on anhydrous, low molecular weight acid/amine mixtures, but this is to our knowledge the first time these observations have been augmented by the use of X-ray scattering. The results therefore bridge the gap between early work on amine/acid mixtures and recent studies of protic and pseudoprotic ionic liquids.
Related Literature
Cascaded multiple recycling amplifications for aptamer-based ultrasensitive fluorescence detection of protein biomarkers
Yao Qin, Daxiu Li, Ruo Yuan, Yun Xiang
DOI: 10.1039/C9AN01674K
A fluorescent probe based on aggregation-induced emission for hydrogen sulfide-specific assaying in food and biological systems
Lingfeng Xu, Ling Ni, Lihe Sun, Fang Zeng, Shuizhu Wu
DOI: 10.1039/C9AN01582E
Nano-analytical characterization of endogenous minerals in healthy placental tissue: mineral distribution, composition and ultrastructure
Elena Tsolaki, Louis Didierlaurent, Samuel Staubli, Robert Zboray, Antonia Neels, Dörthe Dietrich, Pius Manser, Lotus May Desbiolles, Sebastian Leschka, Simon Wildermuth, Sandro Lehner, Pascale Chavatte-Palmer, Wolfram Jochum, Peter Wick, Tina Bürki-Turnherr, Tina Fischer, René Hornung, Sergio Bertazzo
DOI: 10.1039/C9AN01312A
A fully battery-powered inexpensive spectrophotometric system for high-sensitivity point-of-care analysis on a microfluidic chip
Maowei Dou, Juan Lopez, Misael Rios, Oscar Garcia, Chuan Xiao, Michael Eastman, XiuJun Li
DOI: 10.1039/C6AN00370B
Fluorescence array-based sensing of nitroaromatics using conjugated polyelectrolytes
Yu Zong Chen
DOI: 10.1039/C6AN00678G
Sensitive detection of polycyclic aromatic hydrocarbons with gold colloid coupled chloride ion SERS sensor
Xiaoyong Liao, You Li, Hongying Cao, Yishu Zhao, Daniel P. Cassidy
DOI: 10.1039/C9AN01540J
Investigating the effect of Ag nanocube polydispersity on gap-mode SERS enhancement factors
Tyler J. Dill, Matthew J. Rozin, Eric R. Brown, Stephen Palani, Andrea R. Tao
DOI: 10.1039/C6AN00212A
A two-photon fluorescent probe for bio-imaging of formaldehyde in living cells and tissues
Jun-Bin Li, Qian-Qian Wang, Lin Yuan, Yong-Xiang Wu, Xiao-Xiao Hu, Xiao-Bing Zhang, Weihong Tan
DOI: 10.1039/C6AN00473C
Approaches towards molecular amplification for sensing
Sean Goggins, Christopher G. Frost
DOI: 10.1039/C6AN00348F
Enantioseparation of amino alcohol drugs by nonaqueous capillary electrophoresis with a maltobionic acid-based ionic liquid as the chiral selector
DOI: 10.1039/C9AN01162E
You might also like
What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?
When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...
What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?
When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...
How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?
Waste containing this compound (CAS: 62921-74-8) should be handled according to ...
How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?
Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...
How is 5-({4-[(2S,4R)-4-Hydroxy-2-methyltetrahydro-2H-pyran-4-yl]-2-thienyl}sulfanyl)-1-methyl-1,3-dihydro-2H-indol-2-one (CAS: 166882-70-8) typically synthesized?
This compound can be synthesized using a multi-step process involving the conjug...
Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?
There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...
How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?
Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...
How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?
Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...
How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?
Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...
How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?
5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![[4-Amino-2-(methylsulfanyl)-5-pyrimidinyl]methanol structure [4-Amino-2-(methylsulfanyl)-5-pyrimidinyl]methanol structure](https://static.chemtradehub.com/structs/588/588-36-3-fc73.webp)



